Crystallography Open Database

Information card for entry 7100290

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Coordinates	7100290.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	(1,3-bis(diisopropylphenyl)imidazole-2-ylidene)copper(ii) acetate
Formula	C31 H42 Cu N2 O4
Calculated formula	C31 H42 Cu N2 O4
SMILES	C1N(c2c(cccc2C(C)C)C(C)C)C(=[Cu]23([O]=C(O2)C)[O]=C(O3)C)N(C=1)c1c(cccc1C(C)C)C(C)C
Title of publication	A new alternative to Stryker's reagent in hydrosilylation: synthesis, structure, and reactivity of a well-defined (carbene)copper(II) acetate complex
Authors of publication	Jaesook Yun.; Daesung Kim.; Hoseop Yun.
Journal of publication	Chemical Communications
Year of publication	2005
a	22.863 ± 0.003 Å
b	8.68 ± 0.004 Å
c	17.977 ± 0.005 Å
α	90°
β	119.275 ± 0.015°
γ	90°
Cell volume	3111.8 ± 1.6 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180104 (current)	2016-03-26	cif/7/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/10/02.	7100290.cif
120677	2014-07-23	cod/ (saulius@koala.ibt.lt) Adding 4906 DOIs identified by CodBot.	7100290.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7100290.cif
966	2010-01-30	cif/ Adding _cod_database_code tags to all COD entries. Adding tag description to the cif_cod.dic dictionary so that COD entries can be validated.	7100290.cif
853	2009-11-16	cif/ Reconstructing spacegroup designators from the symmetry operators were possible. The comands used can be found in the log file reformat-spacegroups-2009.11.14.log committed with the current revision. Only lines that contained spacegroup designators were changed, and all files pass vcif test after the conversion.	7100290.cif
19	2008-01-26	Changing all end-of-line codes from DOS style to UNIX style in all COD CIF files, for more convenient processing: In the cod/cif/ directory: ff \*.cif \| xargs perl -i -pe 's/\r\n/\n/'	7100290.cif
14	2008-01-13	Appending a header with SVN keywords, COD URL and copying policy to all COD CIF files.	7100290.cif
13	2008-01-13	Setting the svn:keywords property to "Author Date Revision URL Id" for all CIF files in the cod/cif directory.	7100290.cif
1	2007-11-30	Adding all .cif files from the COD, downloaded in a Cod.zip file on 2007.02.07 (and the same Cod.zip is downloadable today, on 2007.11.29)	7100290.cif