Phase transitions of the halogen-bridged <i>M</i>^II^–<i>X</i>–<i>M</i>^IV^ mixed-valence complexes [<i>M</i>(en)~2~][<i>M</i>X~2~(en)~2~](ClO~4~)~4~ (<i>M</i> = Pt,Pd; <i>X</i> = Cl, Br). Structural studies of the high- and low-temperature phases of [Pt(en)~2~][PtBr~2~(en)~2~](ClO~4~)~4~
Authors of publication
Toriumi, K.; Yamashita, M.; Kurita, S.; Murase, I.; Ito, T.
Journal of publication
Acta Crystallographica Section B
Year of publication
1993
Journal volume
49
Journal issue
3
Pages of publication
497 - 506
a
13.563 ± 0.002 Å
b
10.939 ± 0.003 Å
c
9.664 ± 0.002 Å
α
90°
β
90°
γ
90°
Cell volume
1433.8 ± 0.5 Å3
Number of distinct elements
7
Space group number
72
Hermann-Mauguin space group symbol
I c m a
Hall space group symbol
-I 2b 2b
Diffraction radiation wavelength
0.71073 Å
Diffraction radiation type
Mo
Has coordinates
Yes
Has disorder
Yes
Has Fobs
No
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