#------------------------------------------------------------------------------ #$Date: 2025-02-09 19:01:10 +0100 (Sun, 09 Feb 2025) $ #$Revision: 297647 $ #$URL: svn://www.crystallography.net/cod/cif/2/02/33/2023383.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2023383 loop_ _publ_author_name 'Nuss, J\"urgen' 'M\"uhle, Claus' 'Hayama, Kyouhei' 'Abdolazimi, Vahideh' 'Takagi, Hidenori' _publ_section_title ; Tilting structures ininverseperovskites,M3TtO (M= Ca, Sr, Ba, Eu;Tt= Si, Ge, Sn, Pb) ; _journal_issue 3 _journal_name_full 'Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials' _journal_page_first 300 _journal_page_last 312 _journal_paper_doi 10.1107/S2052520615006150 _journal_volume 71 _journal_year 2015 _chemical_formula_moiety 'Cs3 Sn O' _chemical_formula_sum 'Ca3 O Sn' _chemical_formula_weight 254.93 _space_group_crystal_system cubic _space_group_IT_number 221 _space_group_name_Hall '-P 4 2 3' _space_group_name_H-M_alt 'P m -3 m' _symmetry_cell_setting cubic _symmetry_space_group_name_H-M 'P m -3 m' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-2013 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 1 _cell_length_a 4.827(3) _cell_length_b 4.827(3) _cell_length_c 4.827(3) _cell_measurement_reflns_used 2160 _cell_measurement_temperature 295(2) _cell_measurement_theta_max 37.06 _cell_measurement_theta_min 4.22 _cell_volume 112.47(12) _computing_cell_refinement 'Bruker Suite (Bruker AXS, 2013)' _computing_data_collection 'Bruker Suite (Bruker AXS, 2013)' _computing_data_reduction 'Bruker Suite (Bruker AXS, 2013)' _computing_structure_refinement 'SHELXL (Sheldrick, 2008)' _computing_structure_solution 'SHELXL (Sheldrick, 2008)' _diffrn_ambient_temperature 295(2) _diffrn_measured_fraction_theta_full 0.972 _diffrn_measured_fraction_theta_max 1.00 _diffrn_measurement_device_type 'SMART APEX II, Bruker AXS' _diffrn_measurement_method \wscan _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0262 _diffrn_reflns_limit_h_max 8 _diffrn_reflns_limit_h_min -8 _diffrn_reflns_limit_k_max 8 _diffrn_reflns_limit_k_min -8 _diffrn_reflns_limit_l_max 8 _diffrn_reflns_limit_l_min -8 _diffrn_reflns_number 2145 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 36.737 _diffrn_reflns_theta_min 4.222 _exptl_absorpt_coefficient_mu 8.905 _exptl_absorpt_correction_T_max 0.275 _exptl_absorpt_correction_T_min 0.175 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; Sheldrick, G. M. (2012) SADABS - Bruker AXS area detector scaling and absorption, version 2012/1, University of G\"ottingen. Germany. ; _exptl_crystal_colour 'dark grey metallic' _exptl_crystal_density_diffrn 3.765 _exptl_crystal_description block _exptl_crystal_F_000 118 _exptl_crystal_size_max 0.120 _exptl_crystal_size_mid 0.100 _exptl_crystal_size_min 0.060 _refine_diff_density_max 0.386 _refine_diff_density_min -0.378 _refine_ls_extinction_coef 0.225(13) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method SHELXL _refine_ls_goodness_of_fit_ref 1.383 _refine_ls_matrix_type full _refine_ls_number_parameters 6 _refine_ls_number_reflns 85 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.383 _refine_ls_R_factor_all 0.0083 _refine_ls_R_factor_gt 0.0083 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details ; w=1/[\s^2^(Fo^2^)+(0.0142P)^2^] where P=(Fo^2^+2Fc^2^)/3 ; _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0224 _refine_ls_wR_factor_ref 0.0224 _reflns_number_gt 85 _reflns_number_total 85 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file dk5032sup1.cif _cod_data_source_block Ca3SnO_295K _cod_original_cell_volume 112.44(18) _cod_database_code 2023383 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.415 _shelx_estimated_absorpt_t_max 0.617 _shelx_hkl_file ; -1 0 0 988.547 34.182 3 0 -1 0 984.694 32.300 2 0 -1 0 989.930 33.946 3 0 0 -1 991.168 34.059 3 0 0 1 959.197 30.087 1 0 0 1 962.747 32.316 2 0 1 0 958.267 30.186 1 1 0 0 976.164 30.058 1 1 0 0 948.624 32.331 2 -1 -1 0 2192.90 72.75 2 -1 -1 0 2112.79 76.61 3 -1 0 -1 2043.74 76.28 3 -1 0 1 2279.49 72.70 2 0 -1 -1 2276.49 73.01 2 0 -1 -1 2169.43 76.44 3 0 -1 1 2156.97 72.55 2 0 1 -1 2177.21 67.92 1 0 1 -1 2370.02 77.01 3 0 1 1 2152.61 67.63 1 1 -1 0 2274.86 67.87 1 1 -1 0 2205.06 72.98 2 1 -1 0 2259.67 76.97 3 1 0 -1 2121.53 67.88 1 1 0 -1 2277.00 76.46 3 1 0 1 2184.30 67.60 1 1 0 1 2100.47 72.87 2 1 1 0 2163.93 67.92 1 -1 -1 -1 7702.26 272.03 2 -1 -1 -1 7719.87 286.36 3 -1 -1 1 8290.80 272.77 2 -1 1 -1 8713.33 286.63 3 1 -1 -1 8265.97 253.09 1 1 -1 -1 9053.12 271.92 2 1 -1 -1 7500.92 286.63 3 1 -1 1 8394.23 253.09 1 1 -1 1 8518.52 272.86 2 1 1 -1 7412.12 253.10 1 1 1 -1 9127.83 286.14 3 1 1 1 7857.95 253.34 1 -2 0 0 8607.55 321.30 3 0 -2 0 9818.91 306.44 2 0 -2 0 9259.81 321.97 3 0 0 -2 9537.20 321.91 3 0 0 2 9017.72 284.81 1 0 0 2 9137.97 305.53 2 0 2 0 9999.99 284.92 1 2 0 0 8574.62 306.25 2 -2 0 -1 734.235 25.704 3 -2 0 1 710.251 24.894 2 -1 -2 0 721.284 24.755 2 -1 -2 0 738.845 25.696 3 -1 2 0 756.019 22.673 1 0 -1 -2 748.113 26.277 3 0 -1 2 732.209 22.818 1 0 -1 2 764.701 24.536 2 0 1 -2 704.345 25.898 3 1 -2 0 756.616 24.676 2 1 -2 0 714.648 25.868 3 1 2 0 722.037 22.848 1 2 0 -1 724.405 22.894 1 2 0 -1 741.222 25.684 3 2 0 1 733.932 22.884 1 2 0 1 746.350 24.702 2 -2 -1 0 728.729 25.060 2 -2 1 0 737.369 25.771 3 -1 0 -2 714.082 25.957 3 -1 0 2 736.109 24.418 2 0 -2 -1 730.581 24.507 2 0 -2 -1 725.887 25.922 3 0 -2 1 748.128 24.714 2 0 2 -1 736.744 22.639 1 0 2 -1 757.167 25.873 3 0 2 1 729.503 22.914 1 1 0 -2 737.173 22.912 1 1 0 -2 741.471 26.173 3 1 0 2 702.269 22.941 1 1 0 2 742.182 24.426 2 2 -1 0 709.246 22.743 1 2 -1 0 701.898 24.631 2 -2 -1 -1 1627.14 53.82 2 -2 -1 -1 1576.60 56.09 3 -2 1 -1 1622.22 56.16 3 -1 -2 -1 1582.71 53.48 2 -1 -2 -1 1586.68 56.14 3 -1 -2 1 1646.78 53.63 2 -1 -1 -2 1628.94 53.39 2 -1 -1 -2 1594.71 56.48 3 -1 -1 2 1648.02 53.41 2 -1 1 -2 1575.81 56.25 3 -1 1 2 1568.35 49.81 1 -1 1 2 1632.87 53.26 2 -1 2 -1 1647.39 56.27 3 -1 2 1 1681.32 49.74 1 1 -2 -1 1647.28 53.36 2 1 -2 -1 1561.06 56.28 3 1 -2 1 1669.55 53.58 2 1 -1 -2 1543.99 56.50 3 1 -1 2 1611.49 49.66 1 1 -1 2 1631.96 53.40 2 1 1 -2 1544.69 49.69 1 1 1 -2 1615.49 56.25 3 1 1 2 1588.24 49.93 1 1 2 -1 1625.99 49.67 1 1 2 -1 1654.82 56.06 3 1 2 1 1604.78 49.86 1 2 -1 -1 1597.95 49.70 1 2 -1 -1 1572.43 53.43 2 2 -1 -1 1592.14 56.15 3 2 -1 1 1599.64 49.57 1 2 -1 1 1542.00 53.46 2 2 1 -1 1618.38 49.81 1 2 1 1 1611.31 49.87 1 -2 -2 0 8019.17 260.50 2 -2 0 -2 6781.77 274.35 3 -2 0 2 8052.65 260.23 2 -2 2 0 7813.63 276.02 3 0 -2 -2 8041.38 260.90 2 0 -2 -2 7183.48 274.64 3 0 -2 2 7758.41 261.72 2 0 2 -2 8334.46 243.31 1 0 2 -2 8646.62 276.04 3 0 2 2 7922.21 244.39 1 2 -2 0 8227.74 243.13 1 2 -2 0 8279.52 262.75 2 2 0 -2 7790.84 244.24 1 2 0 -2 7969.01 274.88 3 2 0 2 7087.48 243.49 1 2 0 2 7960.95 262.25 2 2 2 0 7730.06 244.32 1 2 2 0 8396.61 274.43 3 -2 -2 -1 649.427 22.110 2 -2 -2 -1 627.812 22.586 3 -2 -2 1 657.258 22.199 2 -2 -1 -2 644.638 21.963 2 -2 -1 -2 616.349 22.942 3 -2 -1 2 672.789 22.003 2 -2 1 -2 612.886 22.845 3 -2 2 -1 677.431 22.939 3 -1 -2 -2 642.709 21.603 2 -1 -2 -2 640.397 23.058 3 -1 -2 2 661.980 21.914 2 -1 2 -2 651.181 22.967 3 -1 2 2 643.284 20.332 1 1 -2 -2 626.904 21.424 2 1 -2 -2 643.068 23.199 3 1 -2 2 658.944 19.910 1 1 -2 2 649.722 21.841 2 1 2 -2 636.058 20.106 1 1 2 -2 623.958 22.791 3 1 2 2 634.047 20.458 1 2 -2 -1 651.769 20.116 1 2 -2 -1 623.334 21.711 2 2 -2 -1 633.258 22.909 3 2 -2 1 641.806 19.811 1 2 -2 1 617.568 21.852 2 2 -1 -2 631.360 20.255 1 2 -1 -2 631.293 21.679 2 2 -1 -2 645.226 22.998 3 2 -1 2 631.436 20.094 1 2 -1 2 616.628 21.746 2 2 1 -2 620.676 20.249 1 2 1 -2 647.134 22.916 3 2 1 2 657.052 20.454 1 2 2 -1 675.534 20.303 1 2 2 -1 650.604 22.524 3 2 2 1 638.730 20.394 1 -2 -2 -2 6512.83 215.92 2 -2 -2 -2 6960.20 227.81 3 -2 -2 2 6625.73 217.31 2 -2 2 -2 6247.53 227.94 3 -2 2 2 6849.05 201.01 1 2 -2 -2 6457.27 216.78 2 2 -2 -2 6223.01 227.17 3 2 -2 2 6778.68 201.33 1 2 -2 2 6674.19 215.87 2 2 2 -2 6219.30 200.93 1 2 2 -2 6788.05 228.00 3 2 2 2 6128.26 201.16 1 -3 0 0 721.224 24.602 3 0 -3 0 689.440 23.888 2 0 -3 0 685.624 24.980 3 0 0 -3 710.908 25.392 3 0 0 3 703.543 22.256 1 0 0 3 705.758 23.340 2 0 3 0 714.256 21.906 1 3 0 0 701.199 22.133 1 3 0 0 685.357 24.073 2 -3 0 -1 1210.09 41.88 3 -3 0 1 1135.91 40.56 2 -1 -3 0 1203.52 40.37 2 -1 3 0 1230.72 37.01 1 0 -1 -3 1230.56 42.74 3 0 -1 3 1222.54 37.36 1 0 -1 3 1226.52 39.91 2 0 1 -3 1169.59 42.35 3 0 1 3 1204.44 37.57 1 1 -3 0 1203.33 40.24 2 1 -3 0 1202.40 42.26 3 1 3 0 1219.89 37.25 1 1 3 0 1180.44 42.02 3 3 0 -1 1201.68 37.38 1 3 0 -1 1233.01 41.81 3 3 0 1 1170.69 37.31 1 3 0 1 1176.21 40.32 2 1 0 3 1199.73 39.78 2 3 -1 0 1203.71 37.23 1 3 -1 0 1182.66 40.27 2 3 1 0 1180.95 37.42 1 0 3 1 1217.41 37.33 1 1 0 -3 1155.89 42.58 3 1 0 3 1184.05 37.47 1 0 -3 1 1212.43 40.32 2 0 3 -1 1206.54 36.97 1 0 3 -1 1203.70 42.18 3 0 -3 -1 1140.71 42.21 3 0 -3 -1 1208.92 40.10 2 -1 0 3 1175.42 37.43 1 -1 0 3 1236.27 39.72 2 -3 1 0 1227.84 41.99 3 -1 0 -3 1152.82 42.41 3 -3 -1 0 1204.72 40.74 2 -1 3 -1 5938.29 201.55 3 -1 1 -3 5683.33 201.60 3 -1 1 3 5575.56 178.50 1 3 1 -1 5639.93 178.44 1 3 1 1 5716.63 178.46 1 3 -1 1 5700.82 191.60 2 3 -1 1 5583.04 179.07 1 3 -1 -1 5704.73 178.85 1 3 -1 -1 6035.60 192.64 2 3 -1 -1 5954.66 203.07 3 1 3 -1 6115.40 178.92 1 1 3 -1 5991.56 202.33 3 1 3 1 5825.13 179.07 1 1 -1 3 5820.45 191.90 2 1 1 -3 5661.02 178.32 1 1 1 -3 5975.59 201.70 3 1 1 3 5639.39 178.58 1 -3 -1 -1 5818.23 192.05 2 -3 -1 -1 5588.11 201.39 3 -3 -1 1 5806.91 192.15 2 -3 1 -1 5496.49 202.26 3 -1 -3 -1 5858.88 192.53 2 -1 -3 -1 5715.48 202.61 3 -1 -3 1 6066.83 191.82 2 -1 -1 -3 5950.34 191.86 2 -1 -1 -3 5682.94 201.85 3 -1 -1 3 6112.83 191.32 2 1 -1 3 5898.07 178.37 1 1 -1 -3 5892.89 202.03 3 1 -3 1 5846.75 191.67 2 -1 3 1 5736.67 178.24 1 1 -3 -1 5809.02 191.44 2 1 -3 -1 5571.74 202.50 3 3 0 2 553.373 19.639 2 3 0 2 577.042 18.249 1 3 0 -2 573.265 20.352 3 -3 0 -2 563.908 20.421 3 -3 0 2 574.247 19.947 2 -2 -3 0 580.495 20.019 2 -2 3 0 594.349 17.784 1 -2 3 0 570.710 20.665 3 0 -2 -3 561.599 21.042 3 0 -2 3 573.592 18.024 1 0 -2 3 574.289 19.521 2 0 2 -3 560.344 20.658 3 0 2 3 567.156 18.465 1 2 -3 0 590.605 19.759 2 2 3 0 590.614 18.242 1 2 3 0 579.457 20.203 3 3 0 -2 577.072 18.277 1 0 3 -2 587.975 17.783 1 0 3 -2 576.873 20.620 3 0 3 2 557.684 18.308 1 2 0 -3 562.284 18.272 1 2 0 -3 560.761 20.910 3 2 0 3 567.547 18.323 1 2 0 3 574.822 19.391 2 3 -2 0 549.094 17.891 1 3 -2 0 558.247 19.692 2 3 2 0 568.391 18.322 1 -3 -2 0 560.315 20.212 2 -3 2 0 578.929 20.519 3 -2 0 -3 578.130 20.764 3 -2 0 3 559.823 19.357 2 0 -3 -2 573.218 19.338 2 0 -3 -2 546.322 20.780 3 0 -3 2 566.560 19.746 2 1 -2 3 980.432 32.406 2 1 2 -3 936.306 30.011 1 1 2 -3 935.057 34.128 3 -1 -3 2 943.091 32.624 2 -1 3 -2 970.916 34.198 3 2 1 3 947.386 30.413 1 2 -3 1 1002.60 32.67 2 2 3 -1 965.396 30.129 1 2 3 -1 948.779 33.716 3 -2 3 1 992.630 29.986 1 -3 1 2 975.963 32.686 2 -3 -2 1 950.622 33.078 2 3 -1 2 973.141 29.994 1 3 -1 2 923.215 32.472 2 3 1 -2 928.449 30.221 1 -2 -3 -1 1001.05 32.76 2 -1 -2 -3 932.218 31.941 2 -1 -2 -3 968.823 34.479 3 -3 2 -1 997.971 34.072 3 -2 1 -3 941.845 34.189 3 -1 2 3 959.734 30.356 1 1 3 2 971.377 30.395 1 1 -2 3 979.922 29.943 1 -3 -1 -2 935.829 32.787 2 -3 -1 -2 988.885 33.998 3 -2 -1 3 980.464 32.361 2 1 -3 -2 941.977 34.363 3 3 -2 -1 984.692 34.034 3 2 -1 -3 951.660 34.438 3 -2 -3 -1 969.481 33.794 3 3 -2 -1 915.471 29.967 1 3 -2 -1 926.641 32.451 2 2 -1 -3 984.355 30.304 1 1 -3 -2 972.508 32.170 2 -1 2 -3 955.418 34.239 3 2 3 1 949.309 30.288 1 3 1 2 949.421 30.355 1 -2 -1 -3 981.875 34.376 3 3 -1 -2 958.132 30.179 1 -3 1 -2 962.685 33.996 3 -2 1 3 1050.01 32.18 2 -1 -3 -2 952.836 32.302 2 -1 -3 -2 959.675 34.189 3 1 2 3 937.075 30.471 1 2 -3 -1 981.017 32.441 2 -1 3 2 974.054 30.233 1 -3 -2 -1 957.299 32.971 2 3 -1 -2 945.834 33.967 3 1 -3 2 993.359 32.637 2 1 3 -2 946.142 29.901 1 1 3 -2 939.819 33.983 3 1 -2 -3 912.725 34.540 3 -1 -2 3 965.907 32.383 2 -2 -1 -3 982.480 32.439 2 2 -1 3 967.857 30.110 1 2 -1 3 948.886 32.307 2 2 1 -3 944.788 30.193 1 2 1 -3 935.397 34.292 3 2 -3 -1 923.225 34.180 3 -2 -3 1 963.867 32.885 2 -2 3 -1 966.015 34.168 3 -3 -1 2 1005.25 32.91 2 3 -2 1 957.962 29.763 1 3 -2 1 891.863 32.517 2 3 2 -1 951.587 30.255 1 -3 -2 -2 464.634 17.121 2 -3 -2 -2 488.962 17.389 3 -3 -2 2 497.533 17.336 2 -3 2 -2 484.811 17.660 3 -2 -3 -2 475.489 16.838 2 -2 -3 -2 478.697 17.527 3 -2 -3 2 461.735 17.138 2 -2 -2 -3 499.729 16.677 2 -2 -2 -3 480.210 17.842 3 -2 2 -3 468.028 17.774 3 -2 2 3 487.133 15.749 1 -2 2 3 505.731 16.480 2 -2 3 -2 499.388 17.797 3 -2 3 2 471.742 15.550 1 2 -3 -2 487.137 16.605 2 2 -3 -2 476.785 17.907 3 2 -3 2 481.610 16.986 2 2 -2 -3 491.608 18.121 3 2 -2 3 476.962 15.260 1 2 -2 3 497.658 16.856 2 2 2 -3 510.834 15.619 1 2 2 -3 477.224 17.667 3 2 2 3 486.538 15.986 1 2 3 -2 494.029 15.529 1 2 3 -2 462.909 17.378 3 2 3 2 461.408 15.799 1 3 -2 -2 459.480 15.531 1 3 -2 -2 446.455 16.676 2 3 -2 -2 475.360 17.670 3 3 -2 2 499.205 15.175 1 3 -2 2 512.074 17.036 2 3 2 -2 453.704 15.641 1 3 2 -2 481.419 17.290 3 3 2 2 500.227 15.921 1 -3 -3 0 761.812 26.442 2 -3 0 -3 749.400 27.114 3 -3 0 3 778.966 25.855 2 -3 3 0 767.233 23.494 1 -3 3 0 753.157 27.128 3 0 -3 -3 745.937 27.566 3 0 -3 3 747.477 23.586 1 0 -3 3 763.454 25.850 2 0 3 -3 754.001 27.190 3 0 3 3 741.994 24.184 1 3 -3 0 774.554 25.997 2 3 0 -3 744.158 24.059 1 3 0 -3 752.371 27.090 3 3 0 3 748.492 24.052 1 3 0 3 734.627 25.687 2 3 3 0 742.832 24.057 1 -3 -3 -1 4054.37 132.90 2 -3 -3 1 4072.26 133.11 2 -3 -1 -3 3959.50 132.56 2 -3 -1 -3 3914.98 139.28 3 -3 -1 3 4078.45 132.53 2 -3 1 -3 3953.18 139.25 3 -3 1 3 4237.67 132.41 2 -3 3 -1 3890.87 139.22 3 -3 3 1 4124.48 122.98 1 -1 -3 -3 4044.19 131.91 2 -1 -3 -3 4155.34 139.58 3 -1 -3 3 3976.09 132.45 2 -1 3 -3 4058.34 139.40 3 -1 3 3 4044.68 123.43 1 1 -3 -3 3961.42 139.78 3 1 -3 3 4024.87 132.42 2 1 3 -3 3976.39 122.98 1 1 3 -3 3964.44 139.20 3 1 3 3 3900.77 123.56 1 3 -3 -1 3971.53 132.39 2 3 -3 -1 3888.94 139.18 3 3 -3 1 4111.23 132.65 2 3 -1 -3 3962.37 123.32 1 3 -1 -3 4027.97 139.39 3 3 -1 3 3960.76 123.13 1 3 -1 3 3971.25 132.32 2 3 1 -3 3904.33 123.33 1 3 1 -3 3873.76 139.20 3 3 1 3 3914.75 123.46 1 3 3 -1 3902.86 123.29 1 3 3 1 3934.92 123.43 1 -3 -3 -2 621.535 22.347 2 -3 -3 -2 644.617 22.821 3 -3 -3 2 632.318 22.688 2 -3 -2 -3 635.114 22.223 2 -3 -2 -3 663.047 23.230 3 -3 -2 3 685.804 22.441 2 -3 2 -3 644.671 23.346 3 -3 2 3 631.622 20.612 1 -3 2 3 623.300 21.980 2 -3 3 -2 634.794 23.299 3 -3 3 2 636.180 20.430 1 -2 -3 -3 639.404 21.851 2 -2 -3 -3 659.166 23.346 3 -2 -3 3 647.375 22.359 2 -2 3 -3 634.982 23.402 3 -2 3 3 628.813 20.614 1 2 -3 -3 632.479 23.694 3 2 -3 3 627.330 22.210 2 2 3 -3 630.379 20.400 1 2 3 -3 645.749 23.155 3 2 3 3 624.820 20.873 1 3 -3 -2 635.819 21.989 2 3 -3 -2 610.655 23.333 3 3 -3 2 617.077 22.317 2 3 -2 -3 711.290 23.598 3 3 -2 3 652.496 22.199 2 3 2 -3 624.949 20.583 1 3 2 -3 635.403 23.133 3 3 2 3 640.193 20.885 1 3 3 -2 650.741 20.577 1 3 3 2 606.997 20.778 1 -3 -3 -3 2975.02 97.16 2 -3 -3 -3 2982.66 101.98 3 -3 3 -3 2887.39 102.32 3 -3 3 3 2925.31 90.49 1 3 -3 -3 2903.36 102.55 3 3 -3 3 2863.75 97.32 2 3 3 -3 2903.89 90.43 1 3 3 3 2887.79 90.83 1 -4 0 0 5054.04 176.77 2 -4 0 0 5537.40 185.39 3 0 -4 0 5445.38 176.35 2 0 0 -4 5425.73 185.88 3 0 0 4 5243.08 164.21 1 0 4 0 5603.66 164.08 1 0 4 0 5273.86 185.30 3 4 0 0 5041.80 164.02 1 -4 0 -1 446.296 15.841 3 -4 0 1 440.053 16.227 2 -4 0 1 458.777 15.753 3 -1 -4 0 444.318 15.834 2 -1 4 0 438.659 16.440 3 0 -1 -4 428.416 16.876 3 0 -1 4 442.675 14.495 1 0 -1 4 454.499 15.183 2 0 1 -4 438.429 16.670 3 0 1 4 429.780 14.687 1 1 -4 0 428.233 15.689 2 1 4 0 464.547 14.311 1 1 4 0 433.789 16.187 3 4 0 -1 442.027 14.492 1 4 0 1 456.573 14.471 1 4 0 1 446.038 15.928 2 0 4 1 452.158 14.345 1 1 0 -4 434.299 16.843 3 1 0 4 457.794 14.666 1 1 0 4 438.313 15.020 2 4 -1 0 447.253 14.352 1 4 -1 0 448.341 15.839 2 4 1 0 426.166 14.531 1 0 -4 1 439.922 15.822 2 0 4 -1 462.283 13.953 1 0 4 -1 442.975 16.326 3 -1 0 -4 450.782 16.822 3 -1 0 4 439.040 14.619 1 0 -4 -1 430.549 15.570 2 0 -4 -1 445.156 16.416 3 -4 -1 0 443.196 16.282 2 -4 1 0 454.072 15.999 3 -1 1 -4 820.317 29.886 3 -1 1 4 808.150 26.391 1 -1 4 -1 826.877 29.658 3 -1 4 1 846.932 25.959 1 1 -4 -1 816.811 28.144 2 -1 -4 -1 792.735 29.451 3 -1 -4 1 820.946 28.470 2 -1 -1 -4 818.271 30.074 3 -1 -1 4 822.463 26.212 1 -1 -1 4 846.205 27.735 2 -4 1 -1 845.325 29.280 3 -1 -4 -1 826.274 28.256 2 4 -1 1 755.618 28.290 2 4 1 -1 842.149 26.320 1 -4 -1 -1 826.159 28.839 2 1 1 4 836.670 26.484 1 1 4 -1 880.679 25.921 1 1 -1 -4 838.892 30.221 3 1 -1 4 842.915 26.226 1 1 -1 4 852.316 27.810 2 1 1 -4 808.983 29.953 3 4 1 1 829.089 26.278 1 1 -4 -1 805.928 29.710 3 1 -4 1 805.909 28.356 2 1 4 -1 837.431 29.431 3 1 4 1 826.705 26.146 1 4 -1 -1 822.098 26.103 1 4 -1 -1 816.829 28.435 2 4 -1 1 805.733 25.981 1 -4 -1 1 830.334 28.933 2 2 0 4 4405.53 139.19 1 2 0 4 4744.37 148.95 2 2 0 -4 4424.27 157.53 3 0 4 2 4554.56 139.09 1 2 0 -4 4496.85 139.18 1 -2 0 -4 4556.25 157.40 3 0 -4 -2 4649.16 149.13 2 0 -4 -2 4440.88 157.26 3 0 -4 2 4398.99 149.53 2 0 4 -2 4633.32 157.09 3 -4 0 -2 4548.00 156.73 3 -4 0 2 4475.62 149.82 2 -2 -4 0 4447.10 149.76 2 -4 -2 0 4513.66 150.09 2 -4 2 0 4565.45 156.85 3 0 2 4 4512.53 139.37 1 2 -4 0 4399.51 149.41 2 2 4 0 4524.82 138.95 1 2 4 0 4570.50 156.68 3 4 0 -2 4439.58 139.10 1 4 0 -2 4677.06 156.55 3 4 0 2 4359.95 139.03 1 4 0 2 4390.31 149.48 2 4 -2 0 4305.16 149.45 2 4 2 0 4499.85 139.20 1 4 -2 0 4388.31 138.72 1 -2 4 0 4582.90 157.24 3 0 -2 -4 4534.75 157.64 3 0 -2 4 4557.85 138.93 1 0 -2 4 4688.67 149.10 2 0 2 -4 4445.93 157.27 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4 -2 2 3699.63 127.44 2 -2 -2 4 3841.67 127.06 2 2 4 2 3854.48 118.69 1 2 -2 4 3897.86 118.23 1 2 -2 4 3939.10 127.13 2 2 2 -4 3777.62 118.41 1 2 2 -4 3829.69 134.11 3 2 2 4 3771.37 118.89 1 2 4 -2 3772.60 118.25 1 2 4 -2 3976.13 133.57 3 3 0 4 346.054 11.259 1 -4 0 -3 337.146 12.480 3 -4 0 3 342.761 12.251 2 -3 -4 0 331.671 12.635 2 -3 4 0 315.315 12.639 3 0 -3 -4 334.313 13.145 3 0 -3 4 331.677 10.822 1 0 -3 4 324.499 11.882 2 0 3 -4 322.396 12.728 3 0 3 4 327.211 11.397 1 3 -4 0 313.875 12.105 2 3 4 0 320.947 11.143 1 4 0 -3 332.132 11.230 1 4 0 -3 321.622 12.200 3 4 0 3 317.093 11.112 1 4 0 3 353.590 12.145 2 3 0 4 344.779 11.807 2 4 -3 0 314.835 12.156 2 4 3 0 321.056 11.257 1 0 4 -3 329.515 12.639 3 0 4 3 327.036 11.295 1 3 0 -4 330.380 12.779 3 -4 -3 0 312.008 12.645 2 -4 3 0 325.090 12.452 3 -3 0 -4 336.287 12.795 3 0 -4 -3 329.401 12.963 3 0 -4 3 317.286 12.124 2 3 0 -4 338.984 11.294 1 -4 -3 1 536.634 20.233 2 4 1 -3 557.390 18.240 1 -4 -1 -3 545.235 19.843 2 -4 -1 -3 562.174 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570.640 19.318 2 1 3 4 547.604 18.486 1 1 4 -3 552.171 20.432 3 3 -4 -1 549.090 20.584 3 -3 -4 1 554.603 20.231 2 -3 4 -1 551.639 20.529 3 3 4 1 540.710 18.218 1 4 -1 -3 534.418 18.121 1 4 -1 -3 577.462 20.291 3 3 1 -4 535.416 20.590 3 1 -3 -4 539.455 21.116 3 -3 -1 -4 572.217 19.509 2 4 -2 3 274.213 10.676 2 4 2 -3 265.506 9.817 1 2 -3 4 279.508 10.473 2 -4 -2 -3 283.993 10.846 2 2 3 -4 269.880 11.123 3 3 -2 -4 287.012 11.481 3 -4 3 -2 281.259 11.029 3 -3 2 -4 298.675 11.329 3 3 -4 2 284.781 10.827 2 3 4 -2 285.911 9.704 1 4 -3 -2 275.789 10.521 2 -2 4 -3 278.697 11.251 3 -2 3 4 279.872 9.927 1 4 -3 -2 268.153 10.965 3 2 -4 -3 288.607 11.625 3 -4 2 3 284.379 10.669 2 -3 -4 -2 277.145 10.698 2 4 3 2 272.519 10.025 1 3 2 4 282.156 10.110 1 -3 4 2 282.295 9.574 1 -2 -3 -4 277.414 11.186 3 -3 -2 4 289.278 10.570 2 2 4 3 279.236 10.043 1 2 3 -4 290.752 9.621 1 -4 -3 2 265.240 11.135 2 -2 -4 3 283.271 10.858 2 4 -2 -3 289.223 11.051 3 -4 -3 -2 294.268 10.970 2 2 -3 -4 288.565 11.743 3 3 -4 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404.407 13.405 1 3 3 4 379.776 13.778 1 3 4 -3 420.845 13.381 1 3 4 3 378.001 13.719 1 4 -3 -3 398.033 15.314 3 4 -3 3 405.645 14.759 2 4 3 -3 410.602 13.543 1 4 3 3 377.466 13.715 1 -4 -4 0 2775.66 94.67 2 -4 0 -4 2836.36 98.80 3 -4 4 0 2826.38 98.77 3 0 -4 -4 2861.10 99.37 3 0 -4 4 2791.54 93.91 2 0 4 -4 2763.79 98.87 3 0 4 4 2868.17 87.74 1 4 -4 0 2815.30 94.18 2 4 0 -4 2778.40 87.56 1 4 0 -4 2902.09 98.64 3 4 0 4 2755.90 87.45 1 4 0 4 2822.08 93.82 2 4 4 0 2758.81 87.52 1 -4 -4 -1 216.558 9.143 2 -4 -4 1 216.758 9.432 2 -4 -1 -4 220.581 8.844 2 -4 -1 -4 248.933 9.264 3 -4 -1 4 242.861 8.771 2 -4 1 -4 217.952 9.148 3 -4 4 -1 229.771 9.144 3 -4 4 1 219.289 9.122 3 -1 -4 -4 224.398 9.427 3 -1 -4 4 215.806 8.713 2 -1 4 -4 231.111 9.414 3 -1 4 4 213.720 8.143 1 1 -4 -4 215.383 9.708 3 1 -4 4 210.969 8.643 2 1 4 -4 206.952 9.095 3 1 4 4 220.494 8.366 1 4 -4 -1 224.003 8.830 2 4 -4 1 216.505 8.949 2 4 -1 -4 217.684 8.191 1 4 -1 -4 232.549 9.156 3 4 -1 4 228.183 7.888 1 4 -1 4 221.443 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14.141 1 5 1 -2 432.425 14.407 1 5 2 1 439.658 14.520 1 -2 -1 -5 419.653 16.594 3 -1 -5 -2 424.877 16.131 3 2 5 1 445.757 14.276 1 1 -5 2 429.855 15.711 2 -5 2 1 446.663 15.752 3 1 5 -2 415.111 15.959 3 2 -1 5 438.346 14.324 1 2 1 -5 413.686 16.547 3 5 1 2 420.182 14.371 1 -1 2 -5 429.549 16.552 3 -2 1 5 429.117 14.601 1 -5 -1 2 411.573 15.945 2 1 2 5 428.555 14.660 1 2 -5 -1 427.185 15.412 2 2 -5 -1 442.820 16.432 3 -1 5 2 447.371 14.166 1 -2 -5 1 418.752 15.910 2 -2 5 -1 399.131 16.186 3 -5 -2 -1 447.687 16.221 2 2 5 1 415.949 15.768 3 5 2 -1 424.806 14.427 1 1 -2 -5 438.586 16.772 3 -1 -2 5 426.225 14.229 1 5 -2 1 429.145 15.740 2 -1 -5 -2 430.241 15.285 2 5 -1 -2 420.896 14.246 1 2 2 5 261.057 9.748 1 2 2 -5 253.991 10.918 3 2 -2 5 288.619 9.930 2 2 -2 -5 257.900 11.088 3 -2 2 -5 263.341 10.950 3 -2 2 5 258.175 9.601 1 -2 5 -2 260.921 10.701 3 5 -2 -2 249.307 10.262 2 5 -2 2 261.227 10.400 2 2 -5 2 250.486 10.325 2 5 2 2 280.796 9.652 1 -2 -5 2 250.344 10.533 2 -2 -2 -5 250.245 10.820 3 -2 -2 5 271.073 9.416 1 -5 2 -2 272.849 10.365 3 -5 2 2 262.331 10.567 2 -2 -5 -2 261.019 10.067 2 -2 -5 -2 246.029 10.282 3 2 5 2 284.340 9.530 1 -5 -2 -2 262.322 10.645 2 5 -2 -2 262.613 9.240 1 2 -5 -2 287.606 10.035 2 2 -5 -2 255.600 10.876 3 -5 -2 2 268.273 10.782 2 5 2 -2 279.928 9.560 1 2 5 -2 282.628 10.350 3 3 5 0 358.086 12.261 1 5 0 -3 345.957 12.358 1 5 0 3 355.449 12.265 1 5 0 3 355.649 13.474 2 0 3 -5 356.846 14.235 3 3 -5 0 363.679 13.462 2 5 3 0 334.260 12.405 1 0 5 3 379.249 12.480 1 3 0 -5 358.411 14.201 3 3 0 5 365.944 12.448 1 5 -3 0 345.771 13.523 2 -5 3 0 365.662 13.663 3 -3 0 -5 386.277 14.478 3 -3 0 5 353.363 12.556 1 0 -5 -3 367.261 14.301 3 0 -3 -5 404.453 14.662 3 0 -3 5 360.151 12.979 2 -5 -3 0 361.798 14.056 2 -5 0 -3 356.391 13.786 2 -5 0 3 379.324 13.668 2 -3 -5 0 328.691 13.787 2 -3 5 0 365.378 14.129 3 0 -5 3 358.090 13.553 2 0 5 -3 361.503 13.964 3 0 3 5 336.227 12.534 1 -1 -3 -5 2163.04 75.76 3 -1 -5 3 2054.39 71.99 2 -1 3 5 2004.42 66.92 1 -3 5 1 2133.56 75.65 3 5 -1 3 2134.45 66.46 1 5 -1 3 2074.10 71.82 2 5 3 1 2052.05 66.95 1 1 3 -5 2042.42 75.64 3 -1 5 -3 2102.17 75.50 3 1 -5 -3 2114.42 75.92 3 3 -5 1 2046.82 71.90 2 3 5 -1 2192.06 66.59 1 1 5 3 2143.20 66.85 1 3 -1 -5 2116.29 75.72 3 -5 1 3 2113.96 71.99 2 5 1 -3 2091.58 66.87 1 -5 3 -1 2127.55 75.12 3 3 1 5 2182.41 67.04 1 5 -3 -1 2072.68 71.89 2 -5 -3 1 2127.39 72.60 2 1 -3 5 2205.09 71.44 2 -3 1 -5 2168.27 75.78 3 -5 -1 -3 2083.51 72.17 2 -3 -1 -5 2211.96 75.78 3 -5 1 -3 2264.25 75.17 3 3 -1 5 2220.78 66.66 1 -3 -5 1 2090.28 72.56 2 5 -3 1 2098.18 72.05 2 -3 1 5 2155.24 67.07 1 -5 -1 3 2079.83 72.04 2 -1 -3 5 2214.31 71.42 2 -1 3 -5 2205.10 75.86 3 -1 5 3 2268.06 66.79 1 1 -5 3 2073.95 71.88 2 1 5 -3 2183.26 75.32 3 3 5 1 2171.63 66.77 1 5 -1 -3 2135.60 66.79 1 -5 -3 -1 2090.02 72.30 2 -3 5 -1 2091.99 75.50 3 3 1 -5 2159.90 75.70 3 -5 3 1 2195.09 75.11 3 -1 -5 -3 2198.86 75.57 3 -1 -3 5 2158.61 66.50 1 1 -3 -5 2109.59 76.03 3 5 3 -1 2075.70 66.85 1 3 1 -5 2130.53 66.86 1 5 1 3 2102.53 66.88 1 1 3 5 2092.65 67.15 1 3 -5 -1 2201.95 71.80 2 -5 3 -2 328.742 12.519 3 -5 2 3 324.469 12.311 2 -3 -5 -2 337.334 12.257 2 2 5 3 298.942 11.242 1 3 -2 -5 317.007 13.126 3 2 -3 5 327.035 11.847 2 2 3 -5 310.314 10.947 1 2 3 -5 319.783 12.924 3 -2 -3 -5 333.243 12.830 3 -3 2 -5 317.101 12.936 3 -5 -3 2 328.471 12.814 2 -5 -2 -3 312.969 12.371 2 -2 5 -3 312.901 12.757 3 5 3 2 321.916 11.434 1 5 2 -3 317.323 11.288 1 2 -5 -3 308.356 13.131 3 3 -5 2 308.673 12.270 2 3 5 -2 378.081 11.125 1 3 2 5 319.992 11.538 1 -2 -5 3 310.740 12.434 2 5 -3 -2 300.775 12.071 2 5 -2 3 305.793 12.218 2 -2 3 5 310.912 11.340 1 5 -3 -2 308.401 10.871 1 5 2 3 312.719 11.404 1 -3 5 -2 291.200 12.616 3 -2 -3 5 319.212 11.778 2 2 -3 -5 322.817 13.345 3 3 -2 5 343.154 11.907 2 3 2 -5 310.461 11.163 1 3 2 -5 288.293 12.669 3 3 5 2 317.469 11.281 1 -3 -5 2 317.209 12.820 2 -3 2 5 311.479 11.403 1 -2 -5 -3 332.534 12.569 3 5 -2 -3 316.061 11.137 1 -5 -2 3 307.807 12.399 2 -2 5 3 330.724 11.075 1 -3 -2 -5 323.424 12.769 3 2 -5 3 315.750 12.245 2 -5 2 -3 336.843 12.520 3 5 3 -2 304.553 11.215 1 -2 3 -5 317.250 12.977 3 5 -3 2 334.680 12.465 2 5 -2 -3 321.748 12.299 3 -5 -3 -2 333.557 12.509 2 3 -5 -2 344.212 11.986 2 3 -5 -2 316.096 12.883 3 2 3 5 310.233 11.600 1 3 5 3 1682.78 53.00 1 -5 -3 3 1646.47 57.25 2 -3 5 -3 1600.81 59.71 3 -3 3 -5 1670.03 59.96 3 -3 -3 5 1681.12 56.47 2 5 3 3 1664.58 53.12 1 -3 3 5 1696.88 52.97 1 3 -5 3 1580.73 56.86 2 3 -3 -5 1624.75 60.20 3 3 -3 5 1674.42 56.53 2 3 3 -5 1710.60 52.69 1 3 3 5 1674.95 53.23 1 -3 -5 3 1701.23 57.42 2 -3 -3 -5 1705.08 59.52 3 5 -3 3 1670.43 57.00 2 5 3 -3 1597.69 52.79 1 -5 -3 -3 1711.08 56.94 2 5 -3 -3 1684.53 59.37 3 3 -5 -3 1645.78 60.15 3 -5 3 3 1720.87 52.66 1 -5 3 -3 1742.92 59.60 3 0 -5 4 187.354 8.131 2 0 5 -4 203.852 8.648 3 -5 -4 0 195.283 8.713 2 -4 -5 0 189.407 8.659 2 0 4 5 184.170 7.670 1 4 -5 0 189.759 8.210 2 4 5 0 197.890 7.497 1 5 0 -4 194.794 7.578 1 -5 0 -4 200.184 8.449 2 0 4 -5 187.811 8.650 3 4 0 -5 203.117 7.694 1 4 0 -5 200.262 8.475 3 5 0 4 194.492 7.439 1 5 -4 0 204.484 8.426 2 -5 4 0 199.241 8.305 3 0 5 4 213.470 7.736 1 -4 5 0 205.321 8.621 3 0 -4 -5 204.966 9.003 3 0 -4 5 194.730 7.903 2 4 0 5 211.339 7.587 1 -4 0 -5 197.978 8.711 3 0 -5 -4 197.425 8.915 3 5 4 0 204.161 7.660 1 -4 5 1 296.576 12.128 3 -5 -1 -4 296.066 11.670 2 -1 -5 4 301.113 11.596 2 -1 -4 -5 318.969 12.446 3 -4 1 -5 278.739 12.083 3 1 5 4 298.267 10.830 1 4 5 -1 296.514 10.503 1 -5 -4 1 286.032 12.157 2 -5 4 -1 287.960 11.776 3 -4 -5 -1 312.955 11.962 2 1 -4 5 298.393 11.269 2 5 -1 4 302.962 11.511 2 5 1 -4 308.865 10.802 1 4 1 5 289.668 10.725 1 -1 4 5 298.349 10.766 1 1 4 -5 300.202 12.221 3 5 -4 -1 299.983 11.645 2 4 -1 -5 289.519 12.055 3 4 -5 1 275.888 11.627 2 -1 5 -4 279.876 12.066 3 5 4 1 306.899 10.863 1 1 -5 -4 297.969 12.638 3 -1 4 -5 285.688 12.227 3 1 5 -4 299.237 12.040 3 5 1 4 297.293 10.705 1 -4 -1 -5 305.928 12.117 3 1 -4 -5 289.064 12.576 3 5 -1 -4 282.664 10.649 1 -5 -4 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176.827 8.412 3 -4 -5 2 166.385 8.150 2 4 2 -5 180.452 6.905 1 -2 -4 5 179.554 7.336 2 2 -5 4 168.032 7.426 2 5 -4 2 167.047 7.688 2 5 4 -2 168.802 6.813 1 -5 4 2 185.664 7.717 3 -4 2 5 174.298 7.054 1 -2 -5 -4 178.390 7.779 3 -2 4 -5 170.608 8.035 3 5 2 4 166.786 6.973 1 -2 5 4 180.191 6.818 1 -4 5 -2 170.700 7.748 3 -5 -2 4 180.572 7.569 2 -5 2 -4 181.999 7.779 3 -5 -4 -2 167.672 7.592 2 4 -2 5 177.540 7.296 2 5 -3 4 238.472 9.681 2 5 3 -4 242.499 8.875 1 4 3 5 238.300 9.210 1 -5 4 -3 232.759 9.853 3 -3 4 5 230.153 8.802 1 -4 3 -5 248.951 10.306 3 3 -4 5 225.636 9.359 2 -3 -5 4 234.374 9.840 2 -3 5 -4 227.325 10.099 3 4 -5 3 235.451 9.798 2 4 5 -3 238.207 8.643 1 3 5 4 247.687 9.170 1 4 -3 -5 228.559 10.229 3 5 4 3 233.278 9.106 1 3 -5 -4 240.826 10.681 3 -5 3 4 228.659 8.791 1 -4 -5 3 224.986 10.156 2 -4 5 -3 224.524 9.979 3 -3 -4 5 232.934 9.456 2 -5 -4 -3 228.504 9.496 2 -3 4 -5 227.727 10.213 3 3 -4 -5 233.283 10.590 3 -4 3 5 225.218 8.863 1 3 4 5 211.684 9.011 1 4 -5 -3 238.031 10.223 3 -5 3 -4 253.820 10.134 3 3 -5 4 228.337 9.531 2 4 5 3 219.641 8.917 1 5 -3 -4 243.692 9.944 3 4 -3 5 259.303 9.602 2 4 3 -5 231.149 8.734 1 5 3 4 224.814 9.010 1 5 -4 3 227.885 9.762 2 5 4 -3 233.676 8.772 1 -5 -3 4 241.931 9.824 2 -5 4 -4 116.350 6.223 3 -4 -5 4 129.913 6.475 2 -4 -4 5 129.712 6.094 2 -4 4 -5 125.422 6.512 3 -4 4 5 123.456 5.530 1 -4 5 -4 129.262 6.471 3 4 -5 -4 157.224 7.152 3 4 -5 4 130.388 6.177 2 4 -4 -5 122.659 6.651 3 4 -4 5 128.541 6.019 2 4 4 -5 130.018 5.487 1 4 4 5 121.790 5.853 1 4 5 4 114.161 5.660 1 5 -4 -4 123.849 6.354 3 5 -4 4 133.416 6.298 2 5 4 -4 130.921 5.550 1 5 4 4 136.057 5.978 1 -5 -5 0 194.943 9.111 2 -5 5 0 208.200 8.928 3 0 -5 -5 205.306 9.427 3 0 -5 5 186.524 8.334 2 0 5 -5 214.907 9.264 3 0 5 5 212.486 8.160 1 5 -5 0 228.144 9.081 2 5 0 -5 214.260 8.222 1 5 5 0 199.734 7.974 1 -5 -5 -1 1295.04 45.97 2 -5 -5 1 1294.52 46.41 2 -5 1 5 1352.97 42.68 1 -5 5 -1 1277.28 47.69 3 -5 5 1 1350.41 47.82 3 -1 -5 -5 1325.97 48.08 3 -1 -5 5 1344.00 45.50 2 -1 5 -5 1345.72 48.20 3 -1 5 5 1299.51 42.42 1 1 -5 -5 1357.55 48.66 3 1 -5 5 1301.22 45.41 2 1 5 -5 1310.28 48.00 3 1 5 5 1336.14 42.69 1 5 -5 -1 1370.44 45.79 2 5 -5 1 1342.75 45.97 2 5 1 -5 1329.05 42.54 1 5 1 5 1312.95 42.41 1 5 5 -1 1284.11 42.29 1 5 5 1 1335.54 42.57 1 -5 -5 -2 192.727 8.347 2 -5 -5 2 200.165 9.107 2 -5 2 -5 203.266 8.790 3 -5 2 5 187.778 7.715 1 -5 5 -2 174.720 8.322 3 -5 5 2 179.567 8.445 3 -2 -5 -5 188.922 8.515 3 -2 -5 5 192.284 8.159 2 -2 5 -5 177.114 8.722 3 -2 5 5 182.772 7.456 1 2 -5 -5 195.250 9.329 3 2 -5 5 192.039 8.033 2 2 5 5 182.439 7.729 1 5 -5 2 198.761 8.602 2 5 -2 5 200.230 8.194 2 5 2 -5 202.993 7.740 1 5 2 5 205.228 7.841 1 5 5 -2 197.193 7.500 1 5 5 2 193.042 7.771 1 -5 -5 3 1083.11 38.91 2 -5 3 -5 1128.17 40.14 3 -5 3 5 1117.87 35.49 1 -5 5 -3 1042.90 39.73 3 -5 5 3 1074.68 39.87 3 -3 -5 5 1105.84 38.12 2 -3 5 -5 1089.66 40.26 3 -3 5 5 1063.90 35.16 1 3 -5 -5 1114.43 40.82 3 3 -5 5 1070.68 37.87 2 3 5 5 1065.62 35.62 1 5 -5 3 1021.39 38.20 2 5 -3 -5 1119.33 40.00 3 5 -3 5 1110.08 38.01 2 5 3 -5 1126.06 35.37 1 5 3 5 1102.87 35.66 1 5 5 -3 1088.29 35.16 1 5 5 3 1080.68 35.55 1 -5 -5 4 139.556 7.262 2 -5 4 -5 152.175 7.426 3 -4 -5 5 141.579 7.035 2 4 -5 5 140.607 6.836 2 5 -4 -5 163.730 7.654 3 5 -4 5 148.215 6.944 2 5 4 -5 163.228 6.482 1 -6 0 0 2311.50 79.51 2 0 -6 0 2350.54 78.75 2 0 0 -6 2386.35 83.28 3 0 0 6 2298.63 73.18 1 0 6 0 2316.62 82.47 3 6 0 0 2366.89 73.00 1 -6 0 -1 183.754 8.360 2 -6 0 1 181.166 8.259 2 -1 -6 0 185.145 7.845 2 -1 6 0 177.696 7.952 3 0 -1 -6 203.211 8.682 3 0 -1 6 182.176 6.976 1 0 1 -6 182.241 8.468 3 0 1 6 169.137 7.082 1 1 -6 0 214.637 7.920 2 1 6 0 184.657 7.713 3 6 0 -1 174.774 6.894 1 6 0 1 182.513 6.889 1 -6 1 0 168.097 8.154 2 -1 0 -6 204.598 8.713 3 -1 0 6 174.309 7.079 1 0 -6 -1 185.012 7.601 2 0 -6 1 181.297 7.860 2 0 6 -1 179.275 7.794 3 0 6 1 195.866 8.024 3 1 0 -6 172.518 8.347 3 1 0 6 196.627 7.179 1 6 -1 0 180.514 6.774 1 6 1 0 191.466 7.095 1 -6 -1 0 185.505 8.387 2 1 -1 -6 367.772 15.101 3 1 1 -6 360.548 15.111 3 1 1 6 371.896 13.112 1 1 6 -1 363.982 14.329 3 1 -1 6 392.086 12.958 1 -1 -1 6 361.795 12.911 1 -1 6 1 381.993 14.806 3 1 -6 -1 372.196 13.896 2 1 -6 1 380.322 14.240 2 -6 -1 -1 358.067 14.630 2 -6 -1 1 382.114 14.830 2 -6 1 1 386.946 14.827 2 -1 -6 -1 361.035 13.972 2 -1 -6 1 357.200 14.284 2 6 1 -1 379.460 12.956 1 6 1 1 377.246 12.987 1 -1 1 -6 382.288 15.300 3 -1 1 6 373.398 13.173 1 -1 6 -1 364.802 14.610 3 6 -1 1 385.725 12.681 1 1 6 1 378.778 14.450 3 6 -1 -1 392.637 12.819 1 -1 -1 -6 388.739 15.274 3 -2 0 6 2088.85 66.11 1 0 -6 2 2127.70 71.19 2 0 6 -2 2076.44 74.27 3 2 0 -6 2132.07 74.92 3 0 -6 -2 2083.72 74.45 3 -6 -2 0 2039.37 71.57 2 -2 0 -6 2101.33 75.05 3 -2 -6 0 2115.25 71.21 2 -6 0 -2 2128.83 71.67 2 -6 0 2 2083.33 71.51 2 0 -2 6 2117.02 65.67 1 0 2 -6 2124.61 75.01 3 0 2 6 2065.03 66.12 1 6 2 0 2022.98 65.91 1 -2 6 0 2085.01 74.59 3 0 -2 -6 2115.11 74.93 3 2 -6 0 2092.14 70.86 2 6 0 -2 2162.77 65.90 1 6 0 2 2106.37 65.74 1 6 -2 0 2036.30 71.15 2 2 0 6 2175.54 66.07 1 2 -1 -6 160.481 7.600 3 6 -2 -1 148.368 7.121 2 6 -2 -1 167.503 6.136 1 -1 2 6 149.260 6.514 1 1 2 -6 150.541 7.562 3 -6 -1 -2 164.133 7.502 2 6 -1 2 156.051 7.176 2 2 1 6 160.411 6.590 1 -2 6 1 161.348 7.462 3 -1 -2 -6 154.784 7.492 3 1 -6 -2 169.447 7.493 3 2 -6 1 146.245 6.939 2 -1 6 -2 162.096 7.222 3 -2 -1 6 162.354 6.513 1 6 1 -2 156.188 6.374 1 -2 1 -6 174.404 7.886 3 1 6 2 164.780 6.219 1 -1 -6 2 169.675 7.389 2 -6 -2 1 144.261 7.337 2 -2 -6 -1 171.220 7.140 2 -6 1 2 152.629 7.345 2 6 2 1 158.663 6.493 1 6 2 -1 154.221 6.397 1 6 -2 1 169.837 7.341 2 -2 -6 1 158.729 7.374 2 -1 -6 -2 175.774 6.828 2 -6 -1 2 156.308 7.390 2 -6 -2 -1 145.995 7.320 2 6 -1 -2 166.438 6.324 1 1 -2 -6 168.396 7.702 3 1 -6 2 168.875 7.226 2 -2 6 -1 148.500 7.196 3 -2 1 6 165.085 6.661 1 -1 -6 -2 170.513 7.172 3 2 6 1 162.983 6.172 1 2 -1 6 161.979 6.364 1 2 1 -6 162.432 7.642 3 -1 2 -6 172.100 7.761 3 1 6 -2 162.619 6.998 3 -2 -1 -6 162.543 7.655 3 -1 -2 6 161.211 6.259 1 6 1 2 167.805 6.512 1 2 -6 -1 156.645 6.811 2 1 2 6 169.338 6.744 1 -2 2 -6 1853.75 67.60 3 -2 2 6 1821.74 59.63 1 2 -6 -2 1875.91 67.47 3 -2 -2 6 1835.85 59.35 1 -2 -2 -6 1991.00 67.49 3 -6 -2 -2 1867.52 64.41 2 -6 -2 2 1813.34 64.44 2 -6 2 2 1903.02 64.52 2 2 2 -6 1863.73 67.56 3 -2 -6 -2 1953.68 63.73 2 -2 -6 2 1899.32 64.52 2 6 2 2 1846.39 59.56 1 6 2 -2 1853.80 59.44 1 6 -2 -2 1895.59 59.17 1 6 -2 2 1897.90 64.25 2 -2 6 -2 1842.25 67.14 3 2 -6 2 1920.31 64.15 2 2 -2 -6 1916.22 67.63 3 2 6 2 1933.95 59.27 1 2 2 6 1902.23 59.78 1 0 -6 3 138.801 6.768 2 -3 -6 0 138.753 6.933 2 -3 6 0 160.646 7.222 3 -6 0 3 146.168 6.846 2 -6 0 -3 170.257 7.415 2 0 -3 -6 162.756 7.414 3 0 3 -6 157.939 7.393 3 -6 -3 0 136.140 7.059 2 -3 0 -6 140.678 7.236 3 -3 0 6 155.514 6.435 1 0 -6 -3 161.210 7.259 3 6 0 3 151.850 6.033 1 0 6 -3 139.447 6.746 3 0 6 3 163.669 6.100 1 0 3 6 149.869 6.330 1 3 -6 0 138.884 6.576 2 3 6 0 164.878 6.006 1 6 0 -3 141.147 6.059 1 3 0 -6 138.908 7.016 3 3 0 6 155.298 6.211 1 6 -3 0 145.771 6.875 2 6 3 0 154.774 6.272 1 -3 1 -6 300.822 12.426 3 1 3 -6 285.674 12.243 3 6 3 1 277.913 10.621 1 -1 -6 3 286.868 11.656 2 3 -6 1 281.390 11.463 2 -1 6 -3 287.364 11.881 3 -6 -1 -3 268.651 11.620 2 1 -6 -3 300.877 12.354 3 -6 1 3 301.380 11.722 2 3 -1 -6 285.380 12.079 3 -3 -1 6 279.835 10.597 1 3 1 6 281.305 10.622 1 6 -3 -1 312.108 11.750 2 -1 3 6 278.780 10.639 1 1 6 3 308.061 10.506 1 -3 -6 -1 298.641 11.615 2 6 -1 3 292.244 11.592 2 6 1 -3 288.949 10.571 1 -3 6 1 285.919 12.095 3 -6 -3 1 287.368 12.013 2 -1 -3 -6 285.187 12.048 3 3 -6 -1 292.739 11.303 2 1 -6 3 287.861 11.539 2 -3 -6 1 282.544 11.959 2 -3 6 -1 276.014 11.900 3 -1 3 -6 272.839 12.219 3 -6 -3 -1 298.253 11.903 2 3 1 -6 283.704 12.024 3 -3 -1 -6 303.209 12.259 3 1 -3 -6 270.575 12.174 3 6 -3 1 306.931 11.854 2 6 3 -1 287.871 10.590 1 -1 -6 -3 297.864 11.921 3 6 -1 -3 290.360 10.471 1 1 6 -3 300.474 11.711 3 6 1 3 304.366 10.623 1 -6 -1 3 290.980 11.642 2 -3 1 6 286.822 10.785 1 1 3 6 277.462 10.742 1 3 6 1 286.377 10.319 1 6 -3 -2 137.723 6.384 2 -2 6 -3 139.401 6.543 3 6 3 2 138.501 5.902 1 -2 -3 -6 136.515 6.479 3 2 -6 -3 136.400 6.820 3 -3 -6 -2 120.383 5.927 2 6 -2 3 141.365 6.456 2 6 2 -3 141.416 5.796 1 -3 6 2 128.344 6.584 3 -3 2 -6 124.735 6.663 3 -6 -3 2 124.861 6.554 2 -2 -6 3 126.659 6.461 2 3 -6 2 126.123 6.242 2 -3 -2 6 132.447 5.657 1 3 -2 -6 126.592 6.643 3 3 2 6 136.085 5.929 1 -2 3 6 128.544 5.789 1 -6 -2 -3 127.654 6.314 2 2 3 -6 142.578 6.875 3 2 6 3 140.780 5.705 1 6 -3 2 137.798 6.527 2 3 6 2 139.981 5.688 1 6 -2 -3 126.689 5.500 1 -3 -6 2 144.357 6.896 2 -3 6 -2 133.334 6.452 3 6 2 3 142.358 5.870 1 -3 -2 -6 124.349 6.364 3 -2 -3 6 139.968 5.557 1 -2 3 -6 127.616 6.712 3 -6 -3 -2 126.027 6.330 2 2 -3 -6 132.404 6.887 3 6 3 -2 140.818 5.774 1 2 3 6 126.590 5.934 1 -3 2 6 127.927 5.815 1 -6 3 2 133.383 6.542 2 2 -6 3 122.931 6.177 2 -6 -2 3 135.960 6.457 2 -3 -6 3 229.967 10.224 2 -3 3 -6 229.942 10.437 3 -3 3 6 245.762 9.144 1 -6 -3 -3 237.611 9.748 2 -6 -3 3 223.573 9.926 2 -3 6 -3 229.851 10.135 3 3 -6 -3 225.123 10.430 3 -3 -3 -6 231.811 9.882 3 -3 -3 6 235.755 8.793 1 6 3 3 236.692 9.098 1 6 -3 3 227.457 9.876 2 6 3 -3 224.826 8.855 1 3 3 6 234.778 9.205 1 3 6 3 225.941 8.836 1 3 -6 3 234.624 9.818 2 3 -3 -6 240.105 10.568 3 -4 -6 0 1499.39 52.60 2 6 0 -4 1518.93 48.34 1 4 0 6 1561.65 48.25 1 -6 0 -4 1499.49 52.41 2 0 6 4 1617.76 48.32 1 4 -6 0 1451.49 51.93 2 -4 0 -6 1562.53 54.90 3 0 -6 -4 1603.84 55.07 3 0 -6 4 1510.31 52.09 2 0 4 -6 1535.48 55.01 3 -6 -4 0 1436.32 52.44 2 -6 4 0 1493.48 54.02 3 6 -4 0 1578.19 52.42 2 6 4 0 1457.27 48.33 1 -4 6 0 1527.06 54.68 3 0 -4 -6 1457.20 54.86 3 4 6 0 1444.90 48.01 1 0 4 6 1515.56 48.55 1 0 6 -4 1516.01 54.55 3 -4 1 -6 108.480 6.012 3 -1 4 6 111.851 5.151 1 4 -1 -6 114.687 5.870 3 -1 -6 4 100.649 5.503 2 -1 6 -4 112.078 5.798 3 1 -6 -4 113.167 6.197 3 4 6 -1 116.739 4.918 1 6 -4 -1 121.991 5.814 2 1 6 4 127.115 5.209 1 4 -6 1 107.233 5.601 2 6 -1 4 112.519 5.593 2 -4 6 1 113.686 5.848 3 -1 -4 -6 98.2194 5.7196 3 -6 -4 1 112.861 6.037 2 -6 -1 -4 110.812 5.688 2 -4 -6 -1 108.938 5.714 2 -6 4 -1 106.515 5.333 3 1 4 -6 116.753 6.074 3 -4 -1 6 117.588 5.298 1 6 4 1 107.787 5.160 1 6 1 -4 112.232 5.139 1 4 1 6 118.672 5.224 1 -4 1 6 113.982 5.351 1 1 -6 4 107.634 5.497 2 4 6 1 116.157 5.058 1 6 4 -1 118.148 5.196 1 6 1 4 101.173 4.907 1 1 4 6 97.4596 5.1108 1 6 -4 1 116.914 5.926 2 1 -4 -6 112.557 6.132 3 6 -1 -4 127.763 5.285 1 -1 4 -6 116.862 6.162 3 -1 -6 -4 121.976 5.942 3 -4 -6 1 106.002 6.059 2 -4 -1 -6 107.854 5.773 3 -6 -4 -1 109.458 5.777 2 1 6 -4 116.140 5.740 3 -4 6 -1 104.915 5.715 3 4 -6 -1 115.994 5.549 2 4 -6 2 1357.03 47.59 2 -4 -6 -2 1349.63 47.30 2 -4 6 2 1310.92 49.78 3 -6 -4 2 1340.65 47.99 2 6 4 2 1375.06 44.28 1 6 2 -4 1378.41 44.10 1 -6 4 -2 1395.96 49.32 3 -4 -2 6 1415.75 44.20 1 6 -2 4 1439.16 47.59 2 -2 -4 -6 1380.13 49.70 3 -2 -6 4 1364.32 47.65 2 -2 4 6 1365.82 44.06 1 2 6 4 1327.06 43.98 1 -4 2 -6 1399.98 50.11 3 4 2 6 1380.88 44.24 1 -2 6 -4 1338.59 49.77 3 6 -4 2 1469.50 47.95 2 -6 -4 -2 1321.74 47.44 2 4 6 2 1363.64 43.93 1 -4 -6 2 1386.34 48.33 2 -4 2 6 1425.70 44.35 1 -6 -2 4 1333.63 47.31 2 6 -2 -4 1397.23 43.98 1 2 -6 4 1302.20 47.30 2 6 2 4 1384.46 44.10 1 6 4 -2 1338.62 43.93 1 -2 4 -6 1419.83 50.28 3 -4 6 -2 1340.59 49.72 3 4 2 -6 1396.30 44.03 1 2 4 6 1371.30 44.39 1 -3 -6 4 94.2044 5.3959 2 6 3 -4 101.122 4.744 1 4 -6 3 97.4200 5.2994 2 3 6 4 84.8559 4.5831 1 6 -3 4 111.891 5.472 2 -6 -4 3 90.1509 5.3657 2 6 4 3 89.0968 4.7648 1 4 -3 -6 91.8524 5.4878 3 -3 4 6 96.2014 4.7348 1 -6 4 -3 96.9576 5.1220 3 -4 3 -6 97.5001 5.6169 3 3 -6 -4 95.2981 5.8615 3 4 3 6 92.7512 4.8777 1 -3 6 -4 92.5688 5.3275 3 -6 3 4 110.067 4.850 1 3 -4 -6 97.1169 5.7790 3 6 -4 3 99.2035 5.3707 2 3 -6 4 101.429 5.227 2 -4 6 -3 94.6416 5.3578 3 4 3 -6 103.685 4.715 1 -4 -6 3 92.3667 5.5790 2 6 3 4 110.225 5.026 1 -6 -3 4 93.4749 5.2039 2 3 4 6 93.8617 4.8888 1 -4 3 6 91.4056 4.7276 1 4 6 3 103.404 4.870 1 -3 4 -6 101.963 5.746 3 6 4 -3 105.377 4.747 1 -6 -5 0 105.297 5.921 2 -5 -6 0 110.155 6.036 2 6 -5 0 112.737 5.869 2 6 5 0 111.776 5.152 1 -6 5 0 106.644 5.470 3 0 -5 -6 108.763 5.987 3 0 5 -6 111.990 6.111 3 0 5 6 100.389 5.085 1 5 6 0 111.465 5.033 1 6 0 -5 95.0394 5.0379 1 -5 0 6 107.542 5.283 1 0 -6 -5 118.053 6.172 3 -5 6 0 109.332 5.732 3 0 6 -5 122.239 6.071 3 0 6 5 107.079 5.092 1 5 -6 0 110.552 5.703 2 0 -6 5 108.069 5.441 2 6 -5 -1 185.439 8.401 2 -5 -1 6 178.957 7.781 1 1 -6 -5 202.447 9.284 3 6 1 -5 180.019 7.643 1 5 -6 1 184.790 8.433 2 -6 -5 1 191.694 8.912 2 -6 5 -1 187.895 8.301 3 -5 -6 -1 184.091 8.500 2 -1 6 -5 184.967 8.732 3 -1 -6 5 179.317 8.157 2 -5 6 1 176.278 8.484 3 -1 -5 -6 189.733 8.681 3 5 1 6 199.384 7.682 1 -1 5 6 189.702 7.682 1 1 5 -6 191.475 8.924 3 -6 1 5 184.806 7.767 1 6 5 1 175.673 7.609 1 1 6 5 179.533 7.555 1 5 6 -1 184.238 7.436 1 -5 1 6 203.071 8.015 1 -6 5 1 185.250 8.269 3 6 5 -1 191.417 7.608 1 5 -6 -1 197.123 8.373 2 1 5 6 185.566 7.793 1 6 -5 1 185.555 8.569 2 1 -6 5 187.637 8.128 2 -6 -5 -1 171.395 8.363 2 -1 5 -6 186.465 8.934 3 5 6 1 190.881 7.610 1 -1 -6 -5 184.951 8.642 3 -5 6 -1 193.206 8.598 3 -5 -6 1 169.388 8.778 2 -6 5 -2 98.3979 5.2501 3 5 2 6 104.079 5.004 1 -2 5 6 101.073 4.813 1 6 -2 5 102.777 5.327 2 -5 6 2 83.6014 5.2143 3 2 6 5 101.560 4.922 1 -6 2 5 99.3697 4.9459 1 -5 2 -6 102.919 5.774 3 -2 -6 5 92.2476 5.1932 2 5 6 2 109.141 5.014 1 -5 6 -2 107.382 5.527 3 -5 2 6 95.0433 4.9558 1 6 2 5 91.6929 4.8139 1 2 -6 5 106.414 5.209 2 -6 -5 -2 102.945 5.370 2 5 2 -6 97.0193 4.8323 1 2 5 6 95.5001 4.9111 1 6 5 -2 98.0387 4.7120 1 -7 0 0 175.878 8.378 2 0 -7 0 193.154 7.957 2 0 0 -7 159.356 8.330 3 0 0 7 169.271 6.993 1 0 7 0 176.891 7.849 3 7 0 0 181.639 6.915 1 -7 0 -1 219.128 9.447 2 -7 0 1 205.776 9.245 2 -1 -7 0 208.991 8.753 2 -1 7 0 192.532 8.793 3 0 -1 -7 192.031 9.186 3 0 -1 7 196.153 7.662 1 0 1 -7 191.596 9.321 3 0 1 7 199.325 7.910 1 1 -7 0 185.860 8.387 2 1 7 0 187.607 8.418 3 7 0 -1 208.054 7.706 1 7 0 1 208.684 7.691 1 0 7 -1 191.544 8.597 3 0 7 1 191.344 8.692 3 1 0 -7 195.687 9.266 3 1 0 7 198.357 7.787 1 7 -1 0 200.018 7.472 1 7 1 0 205.756 7.797 1 0 -7 1 203.305 8.782 2 -7 -1 0 217.835 9.431 2 -7 1 0 198.972 9.284 2 -1 0 -7 182.440 9.225 3 -1 0 7 202.357 7.902 1 0 -7 -1 205.851 8.455 2 1 1 -7 1289.67 47.06 3 -1 -1 7 1254.03 41.04 1 -1 1 -7 1266.31 47.17 3 -7 1 -1 1304.37 45.34 2 -7 1 1 1290.46 45.16 2 -1 -7 -1 1271.81 44.19 2 -1 -7 1 1245.22 44.61 2 -1 -1 -7 1270.03 47.03 3 -7 -1 1 1266.50 45.04 2 7 1 1 1294.70 41.10 1 -1 1 7 1248.29 41.29 1 -7 -1 -1 1302.75 45.20 2 -1 7 1 1259.99 46.53 3 1 -7 -1 1278.03 44.07 2 1 -7 1 1271.89 44.45 2 1 -1 -7 1306.75 46.94 3 1 -1 7 1353.10 41.04 1 -1 7 -1 1273.61 46.41 3 1 1 7 1259.03 41.23 1 1 7 1 1274.45 46.08 3 7 -1 -1 1300.85 40.85 1 7 1 -1 1296.73 41.09 1 -2 0 -7 174.916 8.185 3 -2 0 7 162.714 6.809 1 -7 0 -2 162.258 7.887 2 -7 2 0 156.067 7.850 2 0 7 2 153.705 7.432 3 2 0 -7 163.674 7.819 3 2 0 7 155.745 6.594 1 7 2 0 157.157 6.665 1 7 0 2 170.144 6.489 1 0 -7 2 159.325 7.539 2 0 7 -2 151.959 7.244 3 0 2 -7 164.141 8.089 3 0 2 7 169.279 6.869 1 2 -7 0 157.854 7.193 2 7 0 -2 163.209 6.561 1 0 -2 -7 154.613 7.719 3 -2 7 0 160.309 7.634 3 -7 -2 0 163.743 7.821 2 -2 -7 0 166.049 7.500 2 -7 0 2 133.831 7.361 2 -2 -1 7 190.341 7.501 1 -2 -7 -1 186.780 8.080 2 -7 -2 1 170.354 8.435 2 -1 -2 -7 186.606 8.687 3 -7 -1 -2 178.855 8.548 2 2 -7 1 175.920 8.073 2 7 2 1 189.777 7.507 1 -7 1 2 185.393 8.538 2 2 1 7 180.361 7.472 1 -1 -7 2 196.766 8.601 2 -1 7 -2 172.177 8.216 3 -2 7 1 192.348 8.654 3 -2 1 -7 189.730 9.036 3 1 7 2 188.918 8.201 3 2 -1 -7 175.926 8.529 3 -1 2 7 198.919 7.730 1 7 1 -2 186.349 7.383 1 1 2 -7 173.157 8.751 3 1 2 7 189.801 7.644 1 -7 1 -2 202.477 9.021 2 -7 -2 -1 189.429 8.630 2 7 -1 -2 195.881 7.302 1 -2 -1 -7 176.639 8.717 3 7 1 2 170.718 7.260 1 -1 7 2 185.321 8.548 3 1 -7 2 181.854 8.254 2 -1 -2 7 177.720 7.172 1 -1 2 -7 171.111 8.856 3 2 1 -7 175.115 8.653 3 1 -2 -7 176.075 8.571 3 7 -2 1 197.616 8.671 2 7 2 -1 183.312 7.430 1 2 -7 -1 190.115 7.901 2 -2 7 -1 181.626 8.440 3 -7 -1 2 181.158 8.457 2 -2 -7 1 172.685 8.348 2 -2 1 7 188.299 7.678 1 -7 2 1 181.321 8.685 2 7 2 2 151.463 6.260 1 7 2 -2 142.217 6.068 1 2 -2 -7 101.656 6.610 3 2 2 -7 147.354 7.331 3 2 2 7 143.383 6.262 1 2 -7 2 139.246 6.752 2 -2 7 2 145.423 7.136 3 7 -2 2 141.373 7.013 2 -7 -2 -2 157.256 7.148 2 -7 -2 2 138.208 7.023 2 -7 2 2 131.270 6.919 2 -2 -7 2 146.412 7.225 2 -2 -2 -7 147.077 7.117 3 -2 -2 7 141.254 5.971 1 -2 2 -7 123.588 7.203 3 -2 2 7 142.897 6.309 1 -2 7 -2 143.252 6.933 3 7 3 0 166.141 6.943 1 7 -3 0 180.548 8.018 2 0 -7 3 151.337 7.529 2 0 7 -3 156.977 7.441 3 3 0 -7 163.146 7.815 3 -3 0 -7 169.609 8.183 3 -3 0 7 150.190 6.888 1 0 -7 -3 167.132 7.837 3 -7 0 -3 169.430 8.038 2 0 3 -7 157.742 8.149 3 0 3 7 169.342 7.077 1 3 -7 0 151.361 7.224 2 7 0 -3 166.348 6.785 1 -3 -7 0 154.895 7.625 2 -3 7 0 161.691 7.829 3 -7 0 3 168.718 7.645 2 -7 -3 0 154.295 7.795 2 1 3 -7 997.741 39.220 3 -3 -1 7 1047.21 34.49 1 -3 7 1 1041.55 39.00 3 -1 -3 -7 1050.38 38.92 3 7 1 -3 1059.70 34.34 1 -7 -3 1 1023.38 37.57 2 -3 -7 -1 1057.86 37.05 2 1 -7 -3 1043.63 39.12 3 -1 3 7 1007.65 34.44 1 3 -7 1 1004.60 36.96 2 -3 1 -7 1107.70 39.55 3 7 3 1 1078.09 34.54 1 -1 -7 3 1060.84 37.44 2 -1 7 -3 984.785 38.560 3 3 1 7 1058.90 34.41 1 -1 3 -7 1005.45 39.34 3 -3 7 -1 1113.34 39.10 3 -3 1 7 1104.32 34.76 1 1 3 7 1053.19 34.60 1 -7 1 -3 1065.74 37.87 2 -3 -7 1 1085.36 37.76 2 1 -7 3 1075.23 37.26 2 3 1 -7 1022.66 38.84 3 -7 -1 3 1050.78 37.23 2 7 -3 1 1121.29 37.68 2 7 3 -1 985.886 34.209 1 7 1 3 1041.23 34.22 1 -3 -1 -7 1117.30 39.23 3 3 -7 -1 1051.25 36.79 2 -7 -3 -1 1063.22 37.48 2 -7 3 1 1096.98 37.87 2 7 -1 -3 1042.62 34.15 1 3 -2 -7 147.815 7.584 3 -2 3 7 138.215 6.510 1 -7 -2 -3 146.434 7.212 2 7 -2 3 156.332 7.456 2 3 -7 2 150.215 7.211 2 -7 -3 2 152.522 7.492 2 2 3 -7 143.307 7.648 3 3 2 7 145.867 6.557 1 -3 -2 7 157.888 6.597 1 -2 -7 3 154.994 7.559 2 7 3 2 156.655 6.712 1 7 2 -3 149.081 6.475 1 -2 -3 -7 152.470 7.372 3 -3 2 -7 139.127 7.710 3 2 -7 -3 148.008 7.770 3 -3 7 2 139.666 7.457 3 -2 7 -3 153.962 7.426 3 -3 -7 2 149.998 7.725 2 -3 -2 -7 154.502 7.375 3 7 -3 2 179.351 7.848 2 -7 -3 -2 137.368 7.107 2 -2 3 -7 134.388 7.613 3 7 2 3 154.851 6.617 1 -7 3 2 149.883 7.511 2 -3 7 -2 147.392 7.398 3 7 3 -2 159.120 6.535 1 2 3 7 135.649 6.579 1 2 -7 3 145.537 7.160 2 -7 -2 3 151.900 7.287 2 -3 2 7 157.181 6.787 1 7 -2 -3 175.485 6.575 1 7 0 -4 101.958 5.205 1 -4 0 -7 112.522 6.306 3 0 -7 -4 129.912 6.434 3 0 7 -4 102.713 5.891 3 7 -4 0 128.602 6.451 2 -7 0 -4 116.867 6.285 2 -4 -7 0 118.416 6.226 2 0 4 -7 117.458 6.597 3 4 -7 0 117.660 5.887 2 4 1 7 158.706 6.800 1 1 4 -7 137.035 7.865 3 -7 -1 -4 168.969 7.803 2 7 -4 -1 162.055 7.757 2 -4 -7 -1 163.905 7.530 2 -4 1 -7 167.203 8.209 3 7 1 4 157.430 6.736 1 -7 1 -4 153.691 7.930 2 -8 0 0 1042.84 38.61 2 0 -8 0 1090.60 37.77 2 0 0 8 1087.31 34.95 1 0 8 0 1043.34 39.25 3 8 0 0 1093.96 34.72 1 -8 0 1 73.5631 4.9666 2 -1 -8 0 83.2304 4.7419 2 -1 8 0 70.5251 4.5092 3 0 1 8 73.5139 4.0779 1 1 -8 0 75.7712 4.4980 2 8 0 -1 80.7796 4.0033 1 -8 1 0 85.4091 5.2780 2 -1 0 8 70.7872 4.0230 1 0 -8 1 72.3358 4.5961 2 0 8 -1 77.3970 4.5364 3 0 8 1 69.9059 4.4740 3 1 0 -8 68.6893 4.7180 3 1 0 8 83.0091 4.1511 1 8 1 0 86.6547 4.1958 1 -1 -1 8 200.885 8.070 1 1 1 8 193.970 8.139 1 8 1 1 208.644 8.147 1 0 0 0 0.00 0.00 0 ; _shelx_hkl_checksum 68984 _shelx_res_file ; TITL tak15_0m in Pm-3m Ca3SnO at 295K CELL 0.71073 4.8266 4.8266 4.8266 90.000 90.000 90.000 ZERR 1.00 0.0026 0.0026 0.0026 0.000 0.000 0.000 LATT 1 SYMM -X, -Y, Z SYMM -X, Y, -Z SYMM X, -Y, -Z SYMM Z, X, Y SYMM Z, -X, -Y SYMM -Z, -X, Y SYMM -Z, X, -Y SYMM Y, Z, X SYMM -Y, Z, -X SYMM Y, -Z, -X SYMM -Y, -Z, X SYMM Y, X, -Z SYMM -Y, -X, -Z SYMM Y, -X, Z SYMM -Y, X, Z SYMM X, Z, -Y SYMM -X, Z, Y SYMM -X, -Z, -Y SYMM X, -Z, Y SYMM Z, Y, -X SYMM Z, -Y, X SYMM -Z, Y, X SYMM -Z, -Y, -X SFAC O CA SN UNIT 1 3 1 TEMP 24.840 SIZE 0.06 0.10 0.12 ACTA L.S. 4 BOND FMAP 2 PLAN 20 WGHT 0.014200 EXTI 0.224510 FVAR 1.52140 SN 3 0.500000 0.500000 0.500000 10.02083 0.00955 0.00955 = 0.00955 0.00000 0.00000 0.00000 CA 2 0.500000 0.000000 0.000000 10.06250 0.00872 0.01306 = 0.01306 0.00000 0.00000 0.00000 O 1 0.000000 0.000000 0.000000 10.02083 0.00958 0.00958 = 0.00958 0.00000 0.00000 0.00000 HKLF 4 REM tak15_0m in Pm-3m Ca3SnO at 295K REM R1 = 0.0083 for 85 Fo > 4sig(Fo) and 0.0083 for all 85 data REM 6 parameters refined using 0 restraints END WGHT 0.0143 0.0010 REM Highest difference peak 0.386, deepest hole -0.378, 1-sigma level 0.085 Q1 1 0.5000 0.4100 0.4100 10.25000 0.05 0.39 Q2 1 0.3832 0.3832 0.2730 10.50000 0.05 0.20 Q3 1 0.5000 0.1997 0.4063 10.50000 0.05 0.19 Q4 1 0.5000 0.2975 0.2975 10.25000 0.05 0.17 Q5 1 0.3060 0.3060 0.4201 10.50000 0.05 0.13 Q6 1 0.5000 0.1050 0.2782 10.50000 0.05 0.13 Q7 1 0.3983 0.2003 0.2003 10.50000 0.05 0.12 Q8 1 0.1171 0.0000 0.2456 10.50000 0.05 0.12 Q9 1 0.4097 0.2437 0.1252 11.00000 0.05 0.11 Q10 1 0.1124 0.1124 0.1124 10.16667 0.05 0.11 Q11 1 0.0000 0.0000 0.1411 10.12500 0.05 0.09 Q12 1 0.3710 0.2861 0.1849 11.00000 0.05 0.09 Q13 1 0.2597 0.2597 0.2597 10.16667 0.05 0.09 Q14 1 0.3566 0.3566 0.1466 10.50000 0.05 0.07 Q15 1 0.3288 0.2159 0.0000 10.50000 0.05 0.07 Q16 1 0.2202 0.5000 0.5000 10.12500 0.05 0.07 Q17 1 0.4041 0.0000 0.3074 10.50000 0.05 0.06 Q18 1 0.5000 0.1172 0.1723 10.50000 0.05 0.06 Q19 1 0.2560 0.1549 0.1008 11.00000 0.05 0.05 Q20 1 0.1826 0.1826 0.1826 10.16667 0.05 0.05 ; _shelx_res_checksum 1567 _shelxl_version_number 20.13 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, z' '-x, y, -z' 'x, -y, -z' 'z, x, y' 'z, -x, -y' '-z, -x, y' '-z, x, -y' 'y, z, x' '-y, z, -x' 'y, -z, -x' '-y, -z, x' 'y, x, -z' '-y, -x, -z' 'y, -x, z' '-y, x, z' 'x, z, -y' '-x, z, y' '-x, -z, -y' 'x, -z, y' 'z, y, -x' 'z, -y, x' '-z, y, x' '-z, -y, -x' '-x, -y, -z' 'x, y, -z' 'x, -y, z' '-x, y, z' '-z, -x, -y' '-z, x, y' 'z, x, -y' 'z, -x, y' '-y, -z, -x' 'y, -z, x' '-y, z, x' 'y, z, -x' '-y, -x, z' 'y, x, z' '-y, x, -z' 'y, -x, -z' '-x, -z, y' 'x, -z, -y' 'x, z, y' '-x, z, -y' '-z, -y, x' '-z, y, -x' 'z, -y, -x' 'z, y, x' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Sn Sn 0.5000 0.5000 0.5000 0.00955(10) Uani d 1 . . Ca Ca 0.5000 0.0000 0.0000 0.01161(14) Uani d 1 . . O O 0.0000 0.0000 0.0000 0.0096(4) Uani d 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Sn 0.00955(10) 0.00955(10) 0.00955(10) 0.000 0.000 0.000 Ca 0.00872(16) 0.01306(15) 0.01306(15) 0.000 0.000 0.000 O 0.0096(4) 0.0096(4) 0.0096(4) 0.000 0.000 0.000 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle Ca Sn Ca 9_665 . 120.0 Ca Sn Ca 9_665 9 180.0 Ca Sn Ca . 9 60.0 Ca Sn Ca 9_665 5_656 60.0 Ca Sn Ca . 5_656 120.0 Ca Sn Ca 9 5_656 120.0 Ca Sn Ca 9_665 1_566 60.0 Ca Sn Ca . 1_566 180.0 Ca Sn Ca 9 1_566 120.0 Ca Sn Ca 5_656 1_566 60.0 Ca Sn Ca 9_665 5 120.0 Ca Sn Ca . 5 60.0 Ca Sn Ca 9 5 60.0 Ca Sn Ca 5_656 5 180.0 Ca Sn Ca 1_566 5 120.0 Ca Sn Ca 9_665 1_565 60.0 Ca Sn Ca . 1_565 90.0 Ca Sn Ca 9 1_565 120.0 Ca Sn Ca 5_656 1_565 120.0 Ca Sn Ca 1_566 1_565 90.0 Ca Sn Ca 5 1_565 60.0 Ca Sn Ca 9_665 5_556 120.0 Ca Sn Ca . 5_556 120.0 Ca Sn Ca 9 5_556 60.0 Ca Sn Ca 5_656 5_556 90.0 Ca Sn Ca 1_566 5_556 60.0 Ca Sn Ca 5 5_556 90.0 Ca Sn Ca 1_565 5_556 120.0 Ca Sn Ca 9_665 5_655 60.0 Ca Sn Ca . 5_655 60.0 Ca Sn Ca 9 5_655 120.0 Ca Sn Ca 5_656 5_655 90.0 Ca Sn Ca 1_566 5_655 120.0 Ca Sn Ca 5 5_655 90.0 Ca Sn Ca 1_565 5_655 60.0 Ca Sn Ca 5_556 5_655 180.0 Ca Sn Ca 9_665 1_556 120.0 Ca Sn Ca . 1_556 90.0 Ca Sn Ca 9 1_556 60.0 Ca Sn Ca 5_656 1_556 60.0 Ca Sn Ca 1_566 1_556 90.0 Ca Sn Ca 5 1_556 120.0 Ca Sn Ca 1_565 1_556 180.0 Ca Sn Ca 5_556 1_556 60.0 Ca Sn Ca 5_655 1_556 120.0 Ca Sn Ca 9_665 9_655 90.0 Ca Sn Ca . 9_655 60.0 Ca Sn Ca 9 9_655 90.0 Ca Sn Ca 5_656 9_655 60.0 Ca Sn Ca 1_566 9_655 120.0 Ca Sn Ca 5 9_655 120.0 Ca Sn Ca 1_565 9_655 120.0 Ca Sn Ca 5_556 9_655 120.0 Ca Sn Ca 5_655 9_655 60.0 Ca Sn Ca 1_556 9_655 60.0 Ca Sn Ca 9_665 9_565 90.0 Ca Sn Ca . 9_565 120.0 Ca Sn Ca 9 9_565 90.0 Ca Sn Ca 5_656 9_565 120.0 Ca Sn Ca 1_566 9_565 60.0 Ca Sn Ca 5 9_565 60.0 Ca Sn Ca 1_565 9_565 60.0 Ca Sn Ca 5_556 9_565 60.0 Ca Sn Ca 5_655 9_565 120.0 Ca Sn Ca 1_556 9_565 120.0 Ca Sn Ca 9_655 9_565 180.0 O Ca O 1_655 . 180.0 O Ca Sn 1_655 . 90.0 O Ca Sn . . 90.0 O Ca Sn 1_655 1_544 90.0 O Ca Sn . 1_544 90.0 Sn Ca Sn . 1_544 180.0 O Ca Ca 1_655 9_655 45.0 O Ca Ca . 9_655 135.0 Sn Ca Ca . 9_655 60.0 Sn Ca Ca 1_544 9_655 120.0 O Ca Ca 1_655 9_554 135.0 O Ca Ca . 9_554 45.0 Sn Ca Ca . 9_554 120.0 Sn Ca Ca 1_544 9_554 60.0 Ca Ca Ca 9_655 9_554 180.0 O Ca Ca 1_655 5_545 135.0 O Ca Ca . 5_545 45.0 Sn Ca Ca . 5_545 120.0 Sn Ca Ca 1_544 5_545 60.0 Ca Ca Ca 9_655 5_545 120.0 Ca Ca Ca 9_554 5_545 60.0 O Ca Ca 1_655 5_655 45.0 O Ca Ca . 5_655 135.0 Sn Ca Ca . 5_655 60.0 Sn Ca Ca 1_544 5_655 120.0 Ca Ca Ca 9_655 5_655 60.0 Ca Ca Ca 9_554 5_655 120.0 Ca Ca Ca 5_545 5_655 180.0 O Ca Sn 1_655 1_554 90.0 O Ca Sn . 1_554 90.0 Sn Ca Sn . 1_554 90.0 Sn Ca Sn 1_544 1_554 90.0 Ca Ca Sn 9_655 1_554 120.0 Ca Ca Sn 9_554 1_554 60.0 Ca Ca Sn 5_545 1_554 120.0 Ca Ca Sn 5_655 1_554 60.0 O Ca Ca 1_655 5 135.0 O Ca Ca . 5 45.0 Sn Ca Ca . 5 60.0 Sn Ca Ca 1_544 5 120.0 Ca Ca Ca 9_655 5 120.0 Ca Ca Ca 9_554 5 60.0 Ca Ca Ca 5_545 5 90.0 Ca Ca Ca 5_655 5 90.0 Sn Ca Ca 1_554 5 60.0 O Ca Ca 1_655 5_645 45.0 O Ca Ca . 5_645 135.0 Sn Ca Ca . 5_645 120.0 Sn Ca Ca 1_544 5_645 60.0 Ca Ca Ca 9_655 5_645 60.0 Ca Ca Ca 9_554 5_645 120.0 Ca Ca Ca 5_545 5_645 90.0 Ca Ca Ca 5_655 5_645 90.0 Sn Ca Ca 1_554 5_645 120.0 Ca Ca Ca 5 5_645 180.0 O Ca Ca 1_655 9_654 45.0 O Ca Ca . 9_654 135.0 Sn Ca Ca . 9_654 120.0 Sn Ca Ca 1_544 9_654 60.0 Ca Ca Ca 9_655 9_654 90.0 Ca Ca Ca 9_554 9_654 90.0 Ca Ca Ca 5_545 9_654 120.0 Ca Ca Ca 5_655 9_654 60.0 Sn Ca Ca 1_554 9_654 60.0 Ca Ca Ca 5 9_654 120.0 Ca Ca Ca 5_645 9_654 60.0 Ca O Ca 9 . 90.0 Ca O Ca 9 1_455 90.0 Ca O Ca . 1_455 180.0 Ca O Ca 9 5_545 90.0 Ca O Ca . 5_545 90.0 Ca O Ca 1_455 5_545 90.0 Ca O Ca 9 5 90.0 Ca O Ca . 5 90.0 Ca O Ca 1_455 5 90.0 Ca O Ca 5_545 5 180.0 Ca O Ca 9 9_554 180.0 Ca O Ca . 9_554 90.0 Ca O Ca 1_455 9_554 90.0 Ca O Ca 5_545 9_554 90.0 Ca O Ca 5 9_554 90.0 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance Sn Ca 9_665 3.4129(18) Sn Ca . 3.4129(18) Sn Ca 9 3.4129(18) Sn Ca 5_656 3.4129(18) Sn Ca 1_566 3.4129(18) Sn Ca 5 3.4129(18) Sn Ca 1_565 3.4129(18) Sn Ca 5_556 3.4129(18) Sn Ca 5_655 3.4129(18) Sn Ca 1_556 3.4129(18) Sn Ca 9_655 3.4129(18) Sn Ca 9_565 3.4129(18) Ca O 1_655 2.4133(13) Ca O . 2.4133(13) Ca Sn 1_544 3.4129(18) Ca Ca 9_655 3.4129(18) Ca Ca 9_554 3.4129(18) Ca Ca 5_545 3.4129(18) Ca Ca 5_655 3.4129(18) Ca Sn 1_554 3.4129(18) Ca Ca 5 3.4129(18) Ca Ca 5_645 3.4129(18) Ca Ca 9_654 3.4129(18) O Ca 9 2.4133(13) O Ca 1_455 2.4133(13) O Ca 5_545 2.4133(13) O Ca 5 2.4133(13) O Ca 9_554 2.4133(13) _cod_database_fobs_code 2023383