data_2012750
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2002
_journal_volume  58
_journal_page_first  m334
_journal_page_last  m335
_publ_section_title
;
catena-Poly[[tri-n-butyltin]-\m-N-(1-naphthyl)maleamato]
;
loop_
_publ_author_name
  'Parvez, Masood'
  'Ali, Saqib'
  'Ahmad, Sajjad'
  'Bhatti, Moazzam Hussain'
  'Mazhar, Muhammad'
_chemical_name_common  'Tri-n-butyltin-N-(1-naphthyl)-maleamate'
_chemical_formula_moiety  'C26 H37 N O3 Sn'
_chemical_formula_sum  'C26 H37 N O3 Sn'
_chemical_formula_weight  530.26
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
_symmetry_space_group_name_Hall  '-P 1'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
_cell_length_a  9.5705(7)
_cell_length_b  11.7377(9)
_cell_length_c  12.4726(11)
_cell_angle_alpha  97.011(3)
_cell_angle_beta  107.571(4)
_cell_angle_gamma  102.297(6)
_cell_volume  1278.71(18)
_cell_formula_units_Z  2
_cell_measurement_temperature  170(2)
_exptl_crystal_density_diffrn  1.377
_diffrn_ambient_temperature  170(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Sn1 0.22096(5) 0.23271(4) 0.55844(4) 0.0376(2) Uani d . 1 . . Sn
  O1 -0.0238(5) 0.1951(4) 0.4825(5) 0.0463(12) Uani d . 1 . . O
  O2 -0.0329(5) 0.3347(5) 0.6164(5) 0.0498(13) Uani d . 1 . . O
  O3 -0.5023(5) 0.2679(4) 0.6421(4) 0.0420(11) Uani d . 1 . . O
  N1 -0.2518(6) 0.3604(5) 0.7011(5) 0.0387(13) Uani d . 1 . . N
  H1 -0.1686 0.3661 0.6833 0.046 Uiso calc R 1 . . H
  C1 0.2107(8) 0.0846(6) 0.4366(6) 0.0429(17) Uani d . 1 . . C
  H1A 0.3064 0.0604 0.4634 0.051 Uiso calc R 1 . . H
  H1B 0.1264 0.0171 0.4332 0.051 Uiso calc R 1 . . H
  C2 0.1872(8) 0.1093(7) 0.3157(7) 0.0486(18) Uani d . 1 . . C
  H2A 0.0917 0.1337 0.2891 0.058 Uiso calc R 1 . . H
  H2B 0.2716 0.1769 0.3193 0.058 Uiso calc R 1 . . H
  C3 0.1797(9) 0.0041(8) 0.2278(8) 0.062(2) Uani d . 1 . . C
  H3A 0.1044 -0.0665 0.2311 0.075 Uiso calc R 1 . . H
  H3B 0.1433 0.0220 0.1501 0.075 Uiso calc R 1 . . H
  C4 0.3301(9) -0.0257(8) 0.2456(8) 0.056(2) Uani d . 1 . . C
  H4A 0.3169 -0.0944 0.1868 0.084 Uiso calc R 1 . . H
  H4B 0.3664 -0.0447 0.3218 0.084 Uiso calc R 1 . . H
  H4C 0.4045 0.0428 0.2396 0.084 Uiso calc R 1 . . H
  C5 0.2702(8) 0.4026(6) 0.5116(7) 0.0443(17) Uani d . 1 . . C
  H5A 0.3051 0.3926 0.4449 0.053 Uiso calc R 1 . . H
  H5B 0.1739 0.4261 0.4857 0.053 Uiso calc R 1 . . H
  C6 0.3875(9) 0.5052(7) 0.6027(7) 0.0498(19) Uani d . 1 . . C
  H6A 0.4801 0.4789 0.6362 0.060 Uiso calc R 1 . . H
  H6B 0.4156 0.5717 0.5649 0.060 Uiso calc R 1 . . H
  C7 0.3374(11) 0.5513(8) 0.6985(8) 0.063(2) Uani d . 1 . . C
  H7A 0.3140 0.4864 0.7393 0.076 Uiso calc R 1 . . H
  H7B 0.2428 0.5754 0.6656 0.076 Uiso calc R 1 . . H
  C8 0.4563(12) 0.6566(8) 0.7840(8) 0.074(3) Uani d . 1 . . C
  H8A 0.4167 0.6846 0.8432 0.111 Uiso calc R 1 . . H
  H8B 0.4806 0.7210 0.7440 0.111 Uiso calc R 1 . . H
  H8C 0.5484 0.6322 0.8199 0.111 Uiso calc R 1 . . H
  C9 0.2300(8) 0.1950(7) 0.7226(7) 0.0462(18) Uani d . 1 . . C
  H9A 0.3045 0.2616 0.7829 0.055 Uiso calc R 1 . . H
  H9B 0.1292 0.1885 0.7311 0.055 Uiso calc R 1 . . H
  C10 0.2756(9) 0.0788(7) 0.7390(7) 0.0523(19) Uani d . 1 . . C
  H10A 0.2034 0.0142 0.6755 0.063 Uiso calc R 1 . . H
  H10B 0.3774 0.0875 0.7319 0.063 Uiso calc R 1 . . H
  C11 0.2802(12) 0.0409(9) 0.8495(9) 0.075(3) Uani d . 1 . . C
  H11A 0.1773 0.0285 0.8553 0.091 Uiso calc R 1 . . H
  H11B 0.3054 -0.0367 0.8476 0.091 Uiso calc R 1 . . H
  C12 0.3876(17) 0.1233(11) 0.9519(10) 0.102(4) Uani d . 1 . . C
  H12A 0.3820 0.0913 1.0199 0.153 Uiso calc R 1 . . H
  H12B 0.3626 0.2002 0.9560 0.153 Uiso calc R 1 . . H
  H12C 0.4906 0.1342 0.9489 0.153 Uiso calc R 1 . . H
  C13 -0.0952(7) 0.2523(6) 0.5332(7) 0.0416(16) Uani d . 1 . . C
  C14 -0.2644(7) 0.2095(6) 0.4770(6) 0.0417(16) Uani d . 1 . . C
  H14 -0.2976 0.1644 0.4011 0.050 Uiso calc R 1 . . H
  C15 -0.3749(7) 0.2241(6) 0.5157(6) 0.0403(16) Uani d . 1 . . C
  H15 -0.4731 0.1864 0.4614 0.048 Uiso calc R 1 . . H
  C16 -0.3797(7) 0.2864(6) 0.6255(6) 0.0362(15) Uani d . 1 . . C
  C17 -0.2369(8) 0.4304(6) 0.8064(6) 0.0397(16) Uani d . 1 . . C
  C18 -0.3221(9) 0.3905(7) 0.8721(7) 0.0490(18) Uani d . 1 . . C
  H18 -0.3943 0.3149 0.8459 0.059 Uiso calc R 1 . . H
  C19 -0.3030(10) 0.4605(8) 0.9775(7) 0.058(2) Uani d . 1 . . C
  H19 -0.3652 0.4329 1.0207 0.069 Uiso calc R 1 . . H
  C20 -0.1983(11) 0.5661(8) 1.0186(7) 0.059(2) Uani d . 1 . . C
  H20 -0.1847 0.6104 1.0917 0.070 Uiso calc R 1 . . H
  C21 -0.1082(9) 0.6121(7) 0.9542(7) 0.0482(18) Uani d . 1 . . C
  C22 -0.0005(10) 0.7234(8) 0.9929(8) 0.061(2) Uani d . 1 . . C
  H22 0.0131 0.7698 1.0650 0.073 Uiso calc R 1 . . H
  C23 0.0842(11) 0.7662(8) 0.9303(8) 0.063(2) Uani d . 1 . . C
  H23 0.1562 0.8418 0.9586 0.076 Uiso calc R 1 . . H
  C24 0.0662(10) 0.6995(7) 0.8240(7) 0.053(2) Uani d . 1 . . C
  H24 0.1254 0.7300 0.7799 0.064 Uiso calc R 1 . . H
  C25 -0.0363(8) 0.5905(7) 0.7835(7) 0.0453(17) Uani d . 1 . . C
  H25 -0.0471 0.5459 0.7112 0.054 Uiso calc R 1 . . H
  C26 -0.1263(8) 0.5430(6) 0.8461(6) 0.0407(16) Uani d . 1 . . C
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Sn1 0.0266(3) 0.0457(3) 0.0427(3) 0.01165(19) 0.0152(2) 0.0041(2)
  O1 0.030(2) 0.055(3) 0.053(3) 0.013(2) 0.016(2) -0.001(2)
  O2 0.026(2) 0.058(3) 0.059(3) 0.009(2) 0.014(2) -0.010(3)
  O3 0.023(2) 0.057(3) 0.047(3) 0.013(2) 0.014(2) 0.006(2)
  N1 0.029(3) 0.047(3) 0.044(3) 0.013(2) 0.018(3) 0.007(3)
  C1 0.032(4) 0.046(4) 0.047(4) 0.009(3) 0.015(3) -0.002(3)
  C2 0.036(4) 0.066(5) 0.046(4) 0.027(3) 0.012(3) 0.001(4)
  C3 0.043(4) 0.077(6) 0.055(5) 0.021(4) 0.007(4) -0.012(4)
  C4 0.047(4) 0.065(5) 0.058(5) 0.022(4) 0.023(4) -0.005(4)
  C5 0.038(4) 0.049(4) 0.051(5) 0.016(3) 0.018(3) 0.015(3)
  C6 0.048(4) 0.042(4) 0.062(5) 0.012(3) 0.020(4) 0.016(4)
  C7 0.070(6) 0.053(5) 0.062(6) 0.003(4) 0.029(5) 0.007(4)
  C8 0.093(7) 0.055(5) 0.062(6) 0.003(5) 0.023(5) 0.005(4)
  C9 0.032(4) 0.064(5) 0.050(5) 0.015(3) 0.022(3) 0.010(4)
  C10 0.046(4) 0.057(5) 0.060(5) 0.021(4) 0.020(4) 0.017(4)
  C11 0.073(6) 0.076(6) 0.076(7) 0.024(5) 0.018(5) 0.023(5)
  C12 0.131(11) 0.094(9) 0.074(8) 0.025(8) 0.023(8) 0.030(7)
  C13 0.025(3) 0.050(4) 0.048(4) 0.011(3) 0.013(3) 0.003(3)
  C14 0.028(3) 0.052(4) 0.040(4) 0.009(3) 0.009(3) -0.001(3)
  C15 0.021(3) 0.050(4) 0.046(4) 0.011(3) 0.007(3) 0.002(3)
  C16 0.025(3) 0.043(4) 0.042(4) 0.014(3) 0.010(3) 0.009(3)
  C17 0.035(4) 0.051(4) 0.040(4) 0.021(3) 0.014(3) 0.011(3)
  C18 0.045(4) 0.060(5) 0.047(5) 0.015(4) 0.022(4) 0.012(4)
  C19 0.056(5) 0.078(6) 0.050(5) 0.024(4) 0.027(4) 0.017(4)
  C20 0.071(6) 0.075(6) 0.040(5) 0.034(5) 0.025(4) 0.009(4)
  C21 0.051(4) 0.051(4) 0.040(4) 0.020(4) 0.009(4) 0.002(3)
  C22 0.068(6) 0.057(5) 0.045(5) 0.018(4) 0.003(4) 0.001(4)
  C23 0.065(6) 0.053(5) 0.055(5) 0.005(4) 0.008(4) 0.004(4)
  C24 0.056(5) 0.053(5) 0.044(5) 0.011(4) 0.008(4) 0.011(4)
  C25 0.043(4) 0.048(4) 0.039(4) 0.011(3) 0.007(3) 0.005(3)
  C26 0.035(4) 0.047(4) 0.041(4) 0.019(3) 0.008(3) 0.009(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Sn1 C1 . 2.129(7) y
  Sn1 C9 . 2.127(8) y
  Sn1 C5 . 2.142(7) y
  Sn1 O1 . 2.167(5) y
  Sn1 O3 1_655 2.457(4) y
  O1 C13 . 1.293(8) y
  O2 C13 . 1.226(9) y
  O3 C16 . 1.231(8) y
  O3 Sn1 1_455 2.457(4) n
  N1 C16 . 1.339(9) y
  N1 C17 . 1.412(9) y
  N1 H1 . 0.8800 n
  C1 C2 . 1.529(11) n
  C1 H1A . 0.9900 n
  C1 H1B . 0.9900 n
  C2 C3 . 1.521(11) n
  C2 H2A . 0.9900 n
  C2 H2B . 0.9900 n
  C3 C4 . 1.511(11) n
  C3 H3A . 0.9900 n
  C3 H3B . 0.9900 n
  C4 H4A . 0.9800 n
  C4 H4B . 0.9800 n
  C4 H4C . 0.9800 n
  C5 C6 . 1.524(11) n
  C5 H5A . 0.9900 n
  C5 H5B . 0.9900 n
  C6 C7 . 1.499(12) n
  C6 H6A . 0.9900 n
  C6 H6B . 0.9900 n
  C7 C8 . 1.519(12) n
  C7 H7A . 0.9900 n
  C7 H7B . 0.9900 n
  C8 H8A . 0.9800 n
  C8 H8B . 0.9800 n
  C8 H8C . 0.9800 n
  C9 C10 . 1.537(11) n
  C9 H9A . 0.9900 n
  C9 H9B . 0.9900 n
  C10 C11 . 1.490(13) n
  C10 H10A . 0.9900 n
  C10 H10B . 0.9900 n
  C11 C12 . 1.451(15) n
  C11 H11A . 0.9900 n
  C11 H11B . 0.9900 n
  C12 H12A . 0.9800 n
  C12 H12B . 0.9800 n
  C12 H12C . 0.9800 n
  C13 C14 . 1.499(9) n
  C14 C15 . 1.321(10) n
  C14 H14 . 0.9500 n
  C15 C16 . 1.491(10) n
  C15 H15 . 0.9500 n
  C17 C18 . 1.375(10) n
  C17 C26 . 1.429(10) n
  C18 C19 . 1.402(12) n
  C18 H18 . 0.9500 n
  C19 C20 . 1.345(13) n
  C19 H19 . 0.9500 n
  C20 C21 . 1.416(12) n
  C20 H20 . 0.9500 n
  C21 C22 . 1.405(12) n
  C21 C26 . 1.428(10) n
  C22 C23 . 1.350(13) n
  C22 H22 . 0.9500 n
  C23 C24 . 1.397(12) n
  C23 H23 . 0.9500 n
  C24 C25 . 1.364(11) n
  C24 H24 . 0.9500 n
  C25 C26 . 1.403(10) n
  C25 H25 . 0.9500 n