data_2003266
_journal_name_full     'Acta Crystallographica'
_journal_year          1995
_journal_volume    	C51
_journal_page_first    	361
_journal_page_last    	364
_publ_section_title    	
;
[Ru(\h^5^-C~5~H~5~)(\h^4^-C~5~H~4~O){As(CH~3~)~3~}]PF~6~ and
[Ru(\h^5^-C~5~H~5~)(\h^4^-C~5~H~4~O){As(C~6~H~5~)~3~}]PF~6~
;
_chemical_formula_sum    	'C28 H24 As F6 O P Ru'
_chemical_formula_weight    	697.45
_symmetry_space_group_name_H-M    	'P 21/c'
_cell_length_a    	8.076(1)
_cell_length_b    	24.399(4)
_cell_length_c    	13.337(2)
_cell_angle_alpha    	90.00000
_cell_angle_beta    	96.52(1)
_cell_angle_gamma    	90.00000
_cell_volume    	2611.0(7)
_cell_formula_units_Z    	4
_exptl_crystal_density_diffrn    	1.774
_diffrn_radiation_type    	'Mo K\a'
_diffrn_radiation_wavelength    	.71069
_cell_measurement_reflns_used    	48
_cell_measurement_theta_min    	6
_cell_measurement_theta_max    	22
_exptl_absorpt_coefficient_mu    	1.967
_cell_measurement_temperature    	295
_exptl_crystal_description    	plate
_exptl_crystal_size_max    	0.35
_exptl_crystal_size_mid    	0.28
_exptl_crystal_size_min    	0.07
_exptl_crystal_colour    	yellow
_diffrn_measurement_device    	'Philips PW1100 diffractometer'
_diffrn_measurement_method    	\q/2\q
_exptl_absorpt_correction_type    	'by Gaussian integration from crystal shape'
_exptl_absorpt_correction_T_min    	0.54
_exptl_absorpt_correction_T_max    	0.87
_diffrn_reflns_number    	4735
_reflns_number_total    	4586
_reflns_number_observed    	3220
_reflns_observed_criterion    	'[F~o~ > 6\s(F~o~)]'
_diffrn_reflns_av_R_equivalents    	0.010
_diffrn_reflns_theta_max    	25
_diffrn_reflns_limit_h_min    	0
_diffrn_reflns_limit_h_max    	9
_diffrn_reflns_limit_k_min    	0
_diffrn_reflns_limit_k_max    	28
_diffrn_reflns_limit_l_min    	-15
_diffrn_reflns_limit_l_max    	15
_diffrn_standards_number    	3
_diffrn_standards_interval_time    	120
_diffrn_standards_decay_%    	0.8
_refine_ls_structure_factor_coef    	F
_refine_ls_R_factor_obs    	0.028
_refine_ls_wR_factor_obs    	0.027
_refine_ls_goodness_of_fit_obs    	1.14
_refine_ls_number_reflns    	3220
_refine_ls_number_parameters    	345
_refine_ls_hydrogen_treatment    	'H-atom positions refined with riding model (C
_refine_ls_weighting_scheme    	'w=[\s^2^(F~o~)+0.0001F~o~^2^]'
_refine_ls_shift/esd_max    	'<0.01'
_refine_diff_density_max    	0.47
_refine_diff_density_min    	-0.29
_refine_ls_extinction_method    	'SHELX76 (Sheldrick, 1976)'
_refine_ls_extinction_coef    	0.00031(4)
_atom_type_scat_source    	International_Tables_Vol_IV_Table_2.2B
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    Ru .60922(4) .37680(1) .20020(2) .0361(2)
    C(1) .8523(6) .3781(3) .2937(4) .070(3)
    C(2) .8806(6) .3882(3) .1951(5) .080(4)
    C(3) .7956(7) .4374(3) .1652(4) .082(4)
    C(4) .7175(7) .4570(2) .2470(4) .076(4)
    C(5) .7530(7) .4200(2) .3254(4) .070(3)
    C(6) .3347(5) .3272(2) .1216(3) .047(2)
    C(7) .4995(5) .3107(2) .0936(3) .043(2)
    C(8) .5615(5) .3546(2) .0426(3) .049(2)
    C(9) .4677(5) .4019(2) .0607(3) .052(3)
    C(10) .3460(5) .3875(2) .1226(3) .051(3)
    O .2203(3) .2987(1) .1415(2) .068(2)
    As .49669(4) .32769(2) .34355(3) .0315(2)
    C(11) .6674(4) .3097(2) .4544(3) .035(2)
    C(12) .6869(5) .3398(2) .5429(3) .045(2)
    C(13) .8057(5) .3255(2) .6217(3) .053(3)
    C(14) .9059(5) .2810(2) .6127(3) .051(3)
    C(15) .8913(5) .2515(2) .5252(3) .049(3)
    C(16) .7738(5) .2654(2) .4463(3) .044(2)
    C(17) .3936(4) .2556(2) .3251(3) .036(2)
    C(18) .4813(5) .2149(2) .2808(3) .044(2)
    C(19) .4234(5) .1616(2) .2760(3) .053(3)
    C(20) .2775(6) .1488(2) .3143(3) .055(3)
    C(21) .1869(6) .1888(2) .3549(3) .056(3)
    C(22) .2434(5) .2429(2) .3603(3) .044(2)
    C(23) .3467(4) .3722(2) .4137(3) .037(2)
    C(24) .3111(5) .4248(2) .3795(3) .047(2)
    C(25) .2134(6) .4591(2) .4311(3) .065(3)
    C(26) .1523(6) .4410(2) .5169(3) .060(3)
    C(27) .1867(5) .3888(2) .5512(3) .050(3)
    C(28) .2843(5) .3543(2) .5009(3) .042(2)
    P .8345(2) .44766(5) -.15989(9) .0522(7)
    F(1) .7998(4) .3841(1) -.1432(2) .082(2)
    F(2) .9583(3) .4326(1) -.2382(2) .090(2)
    F(3) .6871(3) .4490(1) -.2474(2) .090(2)
    F(4) .7086(4) .4629(1) -.0808(2) .110(2)
    F(5) .9827(4) .4451(1) -.0724(2) .116(3)
    F(6) .8678(3) .5104(1) -.1770(2) .087(2)
    H(1) .8939 .3473 .3337 .078
    H(2) .9455 .3661 .1545 .089
    H(3) .7920 .4544 .1001 .091
    H(4) .6521 .4898 .2484 .084
    H(5) .7154 .4229 .3910 .077
    H(7) .5537 .2761 .1081 .048
    H(8) .6523 .3530 .0020 .054
    H(9) .4848 .4379 .0347 .058
    H(10) .2820 .4122 .1589 .057
    H(12) .6170 .3711 .5497 .050
    H(13) .8177 .3468 .6825 .059
    H(14) .9865 .2705 .6678 .057
    H(15) .9635 .2207 .5187 .054
    H(16) .7652 .2444 .3851 .049
    H(18) .5827 .2239 .2534 .049
    H(19) .4851 .1336 .2460 .059
    H(20) .2389 .1116 .3126 .061
    H(21) .0834 .1796 .3797 .062
    H(22) .1790 .2709 .3882 .049
    H(24) .3542 .4377 .3196 .052
    H(25) .1886 .4955 .4068 .072
    H(26) .0853 .4649 .5529 .067
    H(27) .1425 .3762 .6109 .055
    H(28) .3090 .3180 .5261 .047
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_22
    _atom_site_aniso_U_23
    _atom_site_aniso_U_33
    Ru .0352(2) -.0087(2) .0064(1) .0402(2) -.0002(2) .0335(2)
    C(1) .040(3) -.030(3) -.007(3) .091(4) .015(3) .077(4)
    C(2) .041(3) -.033(3) .023(3) .109(5) -.023(4) .093(4)
    C(3) .084(4) -.068(4) .004(3) .099(5) .013(3) .062(4)
    C(4) .090(4) -.039(3) .008(3) .051(3) -.006(3) .086(4)
    C(5) .079(4) -.047(3) -.003(3) .077(4) -.005(3) .051(3)
    C(6) .042(2) -.010(2) -.008(2) .066(3) .007(2) .029(2)
    C(7) .050(3) -.002(2) .003(2) .043(3) -.003(2) .036(2)
    C(8) .045(2) -.009(2) .008(2) .070(3) -.004(2) .032(2)
    C(9) .061(3) -.006(2) -.002(2) .051(3) .008(2) .042(3)
    C(10) .046(3) .009(2) .004(2) .060(3) -.001(2) .046(3)
    O .044(2) -.030(2) -.012(2) .099(3) .022(2) .059(2)
    As .0284(2) .0007(2) .0048(2) .0352(2) -.0007(2) .0312(2)
    C(11) .028(2) -.004(2) .002(2) .046(3) -.000(2) .030(2)
    C(12) .038(2) .002(2) .004(2) .054(3) -.007(2) .042(2)
    C(13) .045(3) -.009(3) .000(2) .079(4) -.015(2) .036(2)
    C(14) .037(2) .000(2) -.006(2) .077(3) .007(2) .038(2)
    C(15) .037(2) .014(2) .001(2) .060(3) .004(2) .051(3)
    C(16) .038(2) .008(2) -.001(2) .056(3) -.008(2) .038(2)
    C(17) .032(2) -.005(2) -.001(2) .041(2) .002(2) .034(2)
    C(18) .040(2) -.000(2) .001(2) .047(3) -.008(2) .044(2)
    C(19) .059(3) .003(2) -.006(2) .043(3) -.009(2) .053(3)
    C(20) .072(3) -.017(3) -.005(2) .041(3) .001(2) .048(3)
    C(21) .052(3) -.023(3) .006(2) .068(4) .002(2) .048(3)
    C(22) .038(2) -.006(2) .006(2) .055(3) -.006(2) .041(2)
    C(23) .034(2) .007(2) .005(2) .043(3) -.005(2) .036(2)
    C(24) .054(3) .014(2) .014(2) .048(3) .007(2) .042(2)
    C(25) .081(4) .030(3) .023(3) .052(3) .011(3) .065(3)
    C(26) .062(3) .028(3) .018(2) .069(4) -.004(3) .054(3)
    C(27) .043(2) .007(2) .012(2) .068(3) .003(2) .040(2)
    C(28) .040(2) .006(2) .009(2) .046(3) .005(2) .041(2)
    P .0596(7) .0006(6) .0121(6) .0441(7) .0006(6) .0542(7)
    F(1) .113(2) -.006(2) .023(2) .048(2) .011(1) .087(2)
    F(2) .095(2) .009(2) .050(2) .082(2) -.006(2) .102(2)
    F(3) .076(2) -.015(2) -.015(2) .100(2) .028(2) .090(2)
    F(4) .140(3) .019(2) .080(2) .096(2) .004(2) .108(2)
    F(5) .124(3) .004(2) -.044(2) .113(3) -.012(2) .098(2)
    F(6) .091(2) -.007(2) .028(2) .042(2) .001(2) .132(3)