data_1010244
_chemical_name_systematic          'Potassium $-mue-thio-bis(trioxosulfate)'
_chemical_formula_structural       'K2 S3 O6'
_chemical_formula_sum              'K2 O6 S3'
_publ_section_title
;
The Atomic Arrangement in Potassium Trithionate Crystals K~2~ S~3~ O~6~
and the Structure of the Trithionate Radical (S~3~ O~6~)^-2^
;
_publ_author_name                  'Zachariasen, W H'
_journal_name_full
;
Zeitschrift fuer Kristallographie, Kristallgeometrie, Kristallphysik,
Kristallchemie (-144,1977)
;
_journal_coden_ASTM                ZEKGAX
_journal_volume                    89
_journal_year                      1934
_journal_page_first                529
_journal_page_last                 537
_cell_length_a                     9.77(4)
_cell_length_b                     13.63(4)
_cell_length_c                     5.76(2)
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  90
_cell_volume                       767.0
_cell_formula_units_Z              4
_exptl_crystal_density_meas        2.3
_symmetry_space_group_name_H-M     'P n a m'
_symmetry_Int_Tables_number        62
_symmetry_cell_setting             orthorhombic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '1/2+x,1/2-y,1/2-z'
  '-x,-y,1/2+z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2+y,1/2+z'
  'x,y,1/2-z'
  '1/2+x,1/2-y,z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  K1+    1.000
  S2-   -2.000
  S6+    6.000
  O2-   -2.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  K1    K1+    4 c 0.131 0.089 0.25 1.  0 d
  K2    K1+    4 c 0.181 -0.236 0.25 1.  0 d
  S1    S2-    4 c 0.033 0.319 0.25 1.  0 d
  S2    S6+    4 c 0.083 0.472 0.25 1.  0 d
  S3    S6+    4 c 0.306 0.472 0.25 1.  0 d
  O1    O2-    4 c -0.125 0.306 0.25 1.  0 d
  O2    O2-    4 c 0.347 0.583 0.25 1.  0 d
  O3    O2-    8 d 0.083 0.278 0.042 1.  0 d
  O4    O2-    8 d 0.361 0.417 0.042 1.  0 d